425222

Ethyl 2-(bromomethyl)acrylate

98%

• Synonym(s): 2-(Bromomethyl)acrylic acid ethyl ester, Ethyl α-(bromomethyl)acrylate, Ethyl 2-(bromomethyl)-2-propenoate, Ethyl 2-(bromomethyl)propenoate
• Linear Formula: CH₂=C(CH₂Br)CO₂CH₂CH₃
• CAS Number: 17435-72-2
• Molecular Weight: 193.04
• Beilstein: 970108
• MDL number: MFCD00031518
• UNSPSC Code: 12162002
• PubChem Substance ID: 24866620
• NACRES: NA.23

Properties

• Assay: 98%
• refractive index: n20/D 1.479 (lit.)
• bp: 38 °C/0.8 mmHg (lit.)
• density: 1.398 g/mL at 25 °C (lit.)
• storage temp.: −20°C
• SMILES string: [H]\C([H])=C(\CBr)C(=O)OCC
• InChI: 1S/C6H9BrO2/c1-3-9-6(8)5(2)4-7/h2-4H2,1H3
• InChI key: MTCMFVTVXAOHNQ-UHFFFAOYSA-N

Description

General description

Ethyl 2-(bromomethyl)acrylate is an allylic alkylating reagent.

Application

It can be employed as an electrophile for various organometallic compounds. The organometallic derivatives of the compound can be used for the synthesis of α-methylene lactones and lactams. It can also be used for the polymerization of functionalized acrylic monomers.

Safety Information

• Pictograms: GHS07
• Signal Word: Warning
• Hazard Statements: H315,H319,H335
• Precautionary Statements: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Target Organs: Respiratory system
• Storage Class Code: 6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
• WGK: WGK 3
• Flash Point(F): 177.8 °F - closed cup
• Flash Point(C): 81 °C - closed cup
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves