420042
1-Methyl-2-propenylmagnesium chloride solution
0.5 M in THF
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About This Item
Linear Formula:
H2C=CHCH(CH3)MgCl
CAS Number:
Molecular Weight:
114.86
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.22
Recommended Products
Quality Level
reaction suitability
reaction type: Grignard Reaction
concentration
0.5 M in THF
bp
67 °C
density
0.917 g/mL at 25 °C
SMILES string
CC([Mg]Cl)C=C
InChI
1S/C4H7.ClH.Mg/c1-3-4-2;;/h3-4H,1H2,2H3;1H;/q;;+1/p-1
InChI key
RTJGBPYEBKZQGE-UHFFFAOYSA-M
Application
1-Methyl-2-propenylmagnesium chloride is a Grignard type allylating reagent that can be used for the preparation of corresponding homoallylic alcohols by reacting with various aldehydes. It can also be utilized in the synthesis of 3,4-dihydro-4-(1-methyl-2-propen-1-yl)-2(1H)-pyrimidinethione derivatives by treating with 2-mercaptopyrimidine.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 2
Target Organs
Respiratory system
Supplementary Hazards
Storage Class Code
4.3 - Hazardous materials which set free flammable gases upon contact with water
WGK
WGK 3
Flash Point(F)
-4.0 °F - closed cup
Flash Point(C)
-20 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Water accelerated allylation of aldehydes by using water tolerant Grignard-type allylating agents from allylmagnesium chloride and various metallic salts
Fukuma T, et al.
Chemistry Letters (Jpn), 31(3), 376-377 (2002)
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