341010
Bismuth(III) iodide
99%
Synonym(s):
Bismuth triiodide, Triiodobismuthane
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About This Item
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Quality Level
Assay
99%
form
powder
reaction suitability
core: bismuth
reagent type: catalyst
mp
408 °C (lit.)
density
5.78 g/mL at 25 °C (lit.)
SMILES string
I[Bi](I)I
InChI
1S/Bi.3HI/h;3*1H/q+3;;;/p-3
InChI key
KOECRLKKXSXCPB-UHFFFAOYSA-K
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Application
Bismuth(III) iodide or Bismuth triiodide are nontoxic and hence they are used as environmentally friendly catalysts. It can be used as a catalyst in the:
- Chemoselective deprotection of acetals and ketals in water.
- Synthesis of polysubstituted guanidines by guanylation reaction of thioureas with amines.
- Sulfenylation of carbonyl compounds.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B
Storage Class Code
8A - Combustible corrosive hazardous materials
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Bismuth (III) Halides and Sulfate as Highly Efficient Catalyst for the Sulfenylation of Carbonyl and Related Compounds1
Synlett, 1995(09), 984-986 (1995)
The first bismuth (III)-catalyzed guanylation of thioureas
Tetrahedron Letters, 47(39), 6955-6956 (2006)
Environmentally friendly organic synthesis using bismuth compounds: bismuth (III) iodide catalyzed deprotection of acetals in water
Tetrahedron Letters, 49(4), 691-694 (2008)
Chemical communications (Cambridge, England), (44)(44), 5743-5745 (2008-11-15)
The dehydration of a iodobismuthate hybrid built up from Bi(4)I(16) clusters and protonated L-cystine molecules involves an unprecedented reversible dynamic structural change in the solid state leading to 1D BiI(4) chains and 1D helical molecular chains, highlighting the templating effect
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 79(5), 904-908 (2011-05-10)
A novel series of Ge-Te-BiI(3) chalcogenide glasses were prepared by traditional melt-quenching method and the glass-forming region was determined. Properties measurements including density, Vis-NIR and infrared (IR) transmission spectra with FTIR, XRD, DSC were adopted to analyze the composition, structure
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