All Photos(2)
About This Item
Linear Formula:
CH(OCH2CH2CH3)3
CAS Number:
Molecular Weight:
190.28
Beilstein:
1744249
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Quality Level
Assay
97%
refractive index
n20/D 1.407 (lit.)
bp
106-108 °C/40 mmHg (lit.)
density
0.883 g/mL at 25 °C (lit.)
SMILES string
CCCOC(OCCC)OCCC
InChI
1S/C10H22O3/c1-4-7-11-10(12-8-5-2)13-9-6-3/h10H,4-9H2,1-3H3
InChI key
RWNXXQFJBALKAX-UHFFFAOYSA-N
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General description
Gas phase reactions of the rare earth metal cations with tripropyl orthoformate were studied by Fourier transform ion cyclotron resonance mass spectrometry.
Application
Tripropyl orthoformate was used as alcohol donor to investigate the activity and enantioselectivity of Novozym 435 in the esterification of rac-fenoprofen in methylcyclohexane. It may be used as a drying agent during the synthesis of squaraine derivatives.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
10 - Combustible liquids
WGK
WGK 1
Flash Point(F)
161.6 °F - closed cup
Flash Point(C)
72 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Convenient preparation of (s)-fenoprofen by biocatalysed irreversible esterification.
Morrone R, et al.
Rasayan Journal of Chemistry, 1, 732-737 (2008)
Advances in synthesis and application of near-infrared absorbing squaraine dyes.
Hu L, et al.
Royal Society of Chemistry Advances, 3(21), 7667-7676 (2013)
The structure/property relationship in a series of pyrrolic polysquaraines.
Lynch DE and Ewington J.
Synt. Metals, 183, 40-49 (2013)
Synthesis of squaraine dyes under mild conditions: applications for labelling and sensing of biomolecules.
Sleiman MH and Ladame S.
Chemical Communications (Cambridge, England), 50(40), 5288-5290 (2014)
Gas phase reactivity of rare earth metal cations with trialkylorthoformates: synthesis of neutral rare earth alkoxides.
Marchande N, et al
International Journal of Mass Spectrometry, 195, 139-148 (2000)
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