225924

LS-Selectride^® solution

1.0 M in THF

• Synonym(s): Lithium trisiamylborohydride solution
• Linear Formula: LiB[CH(CH₃)CH(CH₃)₂]₃H
• CAS Number: 60217-34-7
• Molecular Weight: 232.18
• MDL number: MFCD00011700
• UNSPSC Code: 12352001
• PubChem Substance ID: 24853533
• NACRES: NA.22

Properties

• form: liquid
• Quality Level: 100
• reaction suitability: reagent type: reductant
• concentration: 1.0 M in THF
• density: 0.903 g/mL at 25 °C
• SMILES string: [Li+].CC(C)C(C)[BH-](C(C)C(C)C)C(C)C(C)C
• InChI: 1S/C15H34B.Li/c1-10(2)13(7)16(14(8)11(3)4)15(9)12(5)6;/h10-16H,1-9H3;/q-1;+1
• InChI key: DGIADQRDWIBVOW-UHFFFAOYSA-N

Description

Application

Reactant for:

• Nucleophilic addition reactions
• Conjugate reduction-initiated cyclization reactions

Legal Information

Selectride is a registered trademark of Merck KGaA, Darmstadt, Germany

Safety Information

• Pictograms: GHS02,GHS08,GHS05,GHS07
• Signal Word: Danger
• Hazard Statements: H225,H260,H314,H335,H336,H351
• Precautionary Statements: P210 - P231 + P232 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Hazard Classifications: Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 1
• Target Organs: Central nervous system, Respiratory system
• Supplementary Hazards: EUH019
• Storage Class Code: 4.3 - Hazardous materials which set free flammable gases upon contact with water
• WGK: WGK 3
• Flash Point(F): 33.8 °F - closed cup
• Flash Point(C): 1 °C - closed cup