214965
Diisobutylaluminum hydride solution
1.0 M in heptane
Synonym(s):
DIBAL, DIBAL-H
About This Item
Recommended Products
form
liquid
Quality Level
reaction suitability
reagent type: reductant
concentration
1.0 M in heptane
density
0.731 g/mL at 25 °C
SMILES string
CC(C)C[AlH]CC(C)C
InChI
1S/2C4H9.Al.H/c2*1-4(2)3;;/h2*4H,1H2,2-3H3;;
InChI key
AZWXAPCAJCYGIA-UHFFFAOYSA-N
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Application
- Synthesis of α-acetoxy ethers by reduction and subsequent acetylation of esters.
- Synthesis of coniferyl, sinapyl, and p-coumaryl alcohol by selective reduction of corresponding cinnamate esters.
- Reduction of secondary phosphine oxides (SPOs) to the corresponding phosphines.
- DIBAL-H can also be used in the hydroalumination of alkene and alkynes.
Signal Word
Danger
Hazard Statements
Hazard Classifications
Aquatic Acute 1 - Aquatic Chronic 1 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Pyr. Liq. 1 - Skin Corr. 1B - STOT SE 3 - Water-react 1
Target Organs
Central nervous system
Supplementary Hazards
Storage Class Code
4.2 - Pyrophoric and self-heating hazardous materials
WGK
WGK 2
Flash Point(F)
30.2 °F
Flash Point(C)
-1 °C
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