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204870

Sigma-Aldrich

Ytterbium(III) chloride hexahydrate

99.998% trace metals basis

Synonym(s):

Ytterbium trichloride hydrate, Ytterbium(III) chloride·6hydrate

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About This Item

Linear Formula:
YbCl3 · 6H2O
CAS Number:
Molecular Weight:
387.49
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.23

Quality Level

Assay

99.998% trace metals basis

form

powder and chunks

reaction suitability

reagent type: catalyst
core: ytterbium

impurities

≤25.0 ppm Trace Rare Earth Analysis

mp

180 °C (dec.) (lit.)

density

2.58 g/mL at 25 °C (lit.)

SMILES string

[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].Cl[Yb](Cl)Cl

InChI

1S/3ClH.6H2O.Yb/h3*1H;6*1H2;/q;;;;;;;;;+3/p-3

InChI key

LEYFXTUKPKKWMP-UHFFFAOYSA-K

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General description

Ytterbium(III) chloride hexahydrate is a white crystalline solid used as a precursor to synthesize nanomaterials and as acatalyst in various organic transformations.

Application

Ytterbium(III) chloride hexahydrate can be used as a precursor:
  • To synthesize ytterbium oxide nanodiscs to fabricate white LEDs.
  • To prepare NaYF4:Yb/Ho/Mn upconversion nanoparticles with good luminescent intensity, for biomedical applications.
  • To fabricate three-dimensional NaYF4:Yb3+/Tm3+hexagonal prisms for near IR photocatalytic H2 evolution.

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Uliana Kostiv et al.
Beilstein journal of nanotechnology, 6, 2290-2299 (2016-01-07)
NaYF4:Yb(3+)/Er(3+) nanoparticles were synthesized by thermal decomposition of lanthanide trifluoroacetates using oleylamine (OM) as both solvent and surface binding ligand. The effect of reaction temperature and time on the properties of the particles was investigated. The nanoparticles were characterized by

Articles

The rare earth elements impact nearly everyone in the world. All of the people living in advanced technological countries and almost all those living in third world countries utilize the rare earths in their everyday living—the car that one drives (gasoline is refined from oil using rare earth catalysts and catalytic converters reduce the polluting emissions from the automotive exhaust), watching the news on TV (the red and green colors in TV screens), the telephones and computers we use to communicate (the permanent magnets in speakers and disc drives), just to name a few examples.

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