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146617

Sigma-Aldrich

Bathophenanthrolinedisulfonic acid disodium salt hydrate

98%

Synonym(s):

Bathophenanthrolinedisulfonic acid disodium salt trihydrate, 4,7-Diphenyl-1,10-phenanthroline-disulfonic acid disodium salt trihydrate, Disodium bathophenanthrolinedisulfonate trihydrate

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About This Item

Empirical Formula (Hill Notation):
C24H14N2Na2O6S2 · 3H2O
CAS Number:
Molecular Weight:
590.53
EC Number:
UNSPSC Code:
12352100
NACRES:
NA.22

Quality Level

Assay

98%

form

powder

mp

300 °C

solubility

water: soluble 100 mg/mL, clear to slightly hazy, yellow (to red)

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General description

Bathophenanthrolinedisulfonic acid disodium salt forms water soluble complexes with palladium and their catalytic role in oxidation of 2-hexanol has been examined.

Application

Bathophenanthrolinedisulfonic acid disodium salt hydrate was used in the preparation of anionic Europium(III) disulfonated bathophenanthroline tris(dibenzoylmethanate) complex.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Intercalation of luminescent Europium (III) complexes in layered double hydroxides.
Sarakha L, et al.
Opt. Mater., 31(3), 562-566 (2009)
Catalytic Conversions in Water. Part 23: Steric Effects and Increased Substrate Scope in the Palladium-Neocuproine Catalyzed Aerobic Oxidation of Alcohols in Aqueous Solvents#.
Brink GJ, et al.
Advanced Synthesis & Catalysis, 345(12), 1341-1352 (2003)
A Paolicchi et al.
Journal of investigative medicine : the official publication of the American Federation for Clinical Research, 47(3), 151-160 (1999-04-13)
gamma-Glutamyl transpeptidase (gamma-GT) is found in serum and in the plasma membranes of virtually all cell types. Its physiologic role is to initiate the hydrolysis of extracellular glutathione (GSH), a tripeptide in which cysteine lies between alpha-glycine and gamma-glutamate residues.
Simone Zanarini et al.
The journal of physical chemistry. B, 112(33), 10188-10193 (2008-07-26)
In this work, the electrochemical and ECL properties of tris[1,10-phenanthrolinediyl-4,7-di(benzenesulfonate)]Ru(II) ([Ru(BPS)3]4-) have been addressed in both strictly aprotic conditions and aqueous buffers. A combined theoretical and experimental approach is presented to focus thermodynamics and kinetic effects of electro-generated species possessing
J M May et al.
Biochemical pharmacology, 57(11), 1275-1282 (1999-05-07)
The role of ascorbic acid in transferrin-independent ferric iron reduction and uptake was evaluated in cultured U-937 monocytic cells. Uptake of 55Fe by U-937 cells was doubled by 100 microM extracellular ascorbate, and by pre-incubation of cells with 100 microM

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