136786
6-Chloro-2-hydroxypyridine
98%
Synonym(s):
6-Chloro-2-pyridinol
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About This Item
Empirical Formula (Hill Notation):
C5H4ClNO
CAS Number:
Molecular Weight:
129.54
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Quality Level
Assay
98%
mp
128-130 °C (lit.)
SMILES string
Oc1cccc(Cl)n1
InChI
1S/C5H4ClNO/c6-4-2-1-3-5(8)7-4/h1-3H,(H,7,8)
InChI key
CLNNBQDAAGDAHI-UHFFFAOYSA-N
General description
6-chloro-2-hydroxypyridine undergoes melt reaction with Os2(O2CCH3)4CI2 at 145°C to yield Os2CI4(chp) and Os2Cl(chp)4.
Application
6-chloro-2-hydroxypyridine was used to study the synthesis, electrochemistry, spectroscopic properties and X-ray crystal structure of Os2Cl(chp)4 (chp = 6-chloro-2- hydroxypyridinate) complex.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Synthesis, spectroscopy, and x-ray structure of chlorotetrakis (6-chloro-2-hydroxypyridinato) diosmium: an unusual Os25+ complex with a polar arrangement of 6-chloro-2-hydroxypyridinato ligands and one axial chloride.
Cotton F, et al.
Inorganic Chemistry, 25(10), 1585-1589 (1986)
Preparation and structural characterization of Os2Cl4(chp)2(L)(chp= 6-chloro-2-hydroxypridinato; L= water, pyridine): a new class of M2X4 (LL)2 complexes possessing an eclipsed conformation
Cotton F, et al.
Inorganic Chemistry, 25(10), 1589-1594 (1986)
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