129259
2,3-Dimethyl-2-butene
98%
Synonym(s):
Tetramethylethylene
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About This Item
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vapor pressure
215 mmHg ( 37.7 °C)
Quality Level
Assay
98%
form
liquid
autoignition temp.
754 °F
refractive index
n20/D 1.412 (lit.)
bp
73 °C (lit.)
mp
−75 °C (lit.)
density
0.708 g/mL at 25 °C (lit.)
storage temp.
2-8°C
SMILES string
C\C(C)=C(\C)C
InChI
1S/C6H12/c1-5(2)6(3)4/h1-4H3
InChI key
WGLLSSPDPJPLOR-UHFFFAOYSA-N
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General description
2,3-Dimethyl-2-butene undergoes hydrolysis to form hydroxyl radical.
Application
2,3-Dimethyl-2-butene was used in the preparation of thexyl NHC-borane (diMe-Imd-BH2thexyl).
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Asp. Tox. 1 - Flam. Liq. 2
Storage Class Code
3 - Flammable liquids
WGK
WGK 3
Flash Point(F)
17.6 °F - closed cup
Flash Point(C)
-8 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Journal of the American Chemical Society, 135(38), 14433-14437 (2013-08-29)
The hydroboration of alkenes of diverse structural types by assorted N-heterocyclic carbene boranes can be accomplished by addition of 5-10% diiodine. For example, reaction of 1,3-dimethylimidazol-2-ylidene borane (diMe-Imd-BH3) with 10% I2 followed by addition of 2,3-dimethyl-2-butene provided the corresponding thexyl
Environmental science & technology, 47(12), 6239-6246 (2013-05-15)
In order to investigate the heterogeneous oxidation kinetics of the herbicide terbuthylazine (TERB), a stable and reproducible generation system of "dark" hydroxyl radical in the gas phase was developed and optimized using a PTR-MS. TERB was adsorbed on silica particles
Biochemical and biophysical research communications, 117(2), 367-371 (1983-12-16)
Although indirect evidence has suggested that liver microsomal cytochrome P-450 can reductively dehalogenate several compounds to carbene metabolites, there has been no direct proof for the formation of these reactive species. We report in this paper that carbenes can be
Xenobiotica; the fate of foreign compounds in biological systems, 26(4), 425-435 (1996-04-01)
1. During anaerobic reductive incubation of liver microsomes, from either the pyridine- or phenobarbital-treated rat, with 1,1-dichloro-1-fluoroethane (HCFC-141b) in the presence of a NADPH-regenerating system, a time- and dose-dependent formation of reactive metabolites was detected as indicated by a depletion
Environmental science & technology, 41(7), 2357-2363 (2007-04-19)
We present a novel method for continuous, stable OH radical production for use in smog chamber studies, especially those focused on organic aerosol aging. Our source produces OH radicals from the reaction of 2,3-dimethyl-2-butene and ozone and is unique as
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