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118303

Sigma-Aldrich

1,9-Decadiene

97%

Synonym(s):

Deca-1,9-diene

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About This Item

Linear Formula:
CH2=CH(CH2)6CH=CH2
CAS Number:
Molecular Weight:
138.25
Beilstein:
1697870
EC Number:
MDL number:
UNSPSC Code:
12352100
eCl@ss:
39010313
PubChem Substance ID:
NACRES:
NA.22

Quality Level

Assay

97%

refractive index

n20/D 1.432 (lit.)

bp

169 °C (lit.)

density

0.75 g/mL at 25 °C (lit.)

SMILES string

C=CCCCCCCC=C

InChI

1S/C10H18/c1-3-5-7-9-10-8-6-4-2/h3-4H,1-2,5-10H2

InChI key

NLDGJRWPPOSWLC-UHFFFAOYSA-N

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General description

1,9-Decadiene acts as comonomer and undergoes acyclic diene metathesis (ADMET) copolymerization with 1, 5-hexadiene to form random linear polybutadiene –polyoctenamer copolymers. It undergoes ADMET copolymerization with divinyltetraethoxydisiloxane to yield siloxylene–vinylene–alkenylene copolymer.

Application

1,9-Decadiene was used in synthesis and characterization of new telechelic polyoctenamers prepared by ADMET polymerization using Grubbs catalyst.

Signal Word

Warning

Hazard Statements

Hazard Classifications

Aquatic Acute 1 - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

105.8 °F - closed cup

Flash Point(C)

41 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Synthesis of ABA triblock copolymers via acyclic diene metathesis polymerization and living polymerization of a-amino acid-N-carboxyanhydrides.
Brzezinska KR and Deming TJ.
Macromolecules, 34(13), 4348-4354 (2001)
ADMET copolymerization of divinyltetraethoxydisiloxane with 1, 9-decadiene catalyzed by Grubbs' catalyst.
Malecka E, et al.
J. Mol. Catal. A: Chem., 190(1), 27-31 (2002)
Brent L Lee et al.
The Journal of chemical physics, 144(24), 245103-245103 (2016-07-03)
The time-resolved parallel artificial membrane permeability assay with fluorescence detection and comprehensive computer simulations are used to study the passive permeation of three aromatic dipeptides-N-acetyl-phenylalanineamide (NAFA), N-acetyltyrosineamide (NAYA), and N-acetyl-tryptophanamide (NATA) through a 1,2-dioleoyl-sn-glycero-3-phospocholine (DOPC) lipid bilayer. Measured permeation times
Acyclic diene metathesis copolymerization of 1, 5-hexadiene and 1, 9-decadiene.
Wagener KB, et al.
Macromolecules, 23(24), 5155-5157 (1990)
Katarzyna Mituła et al.
Polymers, 12(5) (2020-05-10)
The scientific reports on polyhedral oligomeric silsesquioxanes are mostly focused on the formation of completely condensed T8 cubic type structures and recently so-called double-decker derivatives. Herein, we report on efficient synthetic routes leading to trifunctionalized, open-cage silsesquioxanes with alkenyl groups

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