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About This Item
Linear Formula:
CH2=CHCH2C(CH3)3
CAS Number:
Molecular Weight:
98.19
Beilstein:
1731848
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
Recommended Products
vapor pressure
231 mmHg ( 37.7 °C)
Quality Level
Assay
99%
refractive index
n20/D 1.392 (lit.)
bp
72 °C (lit.)
density
0.683 g/mL at 25 °C (lit.)
SMILES string
CC(C)(C)CC=C
InChI
1S/C7H14/c1-5-6-7(2,3)4/h5H,1,6H2,2-4H3
InChI key
KLCNJIQZXOQYTE-UHFFFAOYSA-N
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General description
4,4-Dimethyl-1-pentene is obtained by the S(N)2′ attack of the organolithium on allyl ether.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Asp. Tox. 1 - Flam. Liq. 2
Storage Class Code
3 - Flammable liquids
WGK
WGK 3
Flash Point(F)
10.4 °F - closed cup
Flash Point(C)
-12 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Bailey et al.
Organic letters, 2(4), 489-491 (2000-05-18)
[reaction: see text] Allylic ethers are converted to the corresponding alcohol or phenol in virtually quantitative yield at temperatures below ambient simply by stirring a hydrocarbon solution of the ether with 1 molar equiv of tert-butyllithium. The reaction, which produces
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