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  • How do esters and dimethyl sulphide concentrations affect fruity aroma perception of red wine? Demonstration by dynamic sensory profile evaluation.

How do esters and dimethyl sulphide concentrations affect fruity aroma perception of red wine? Demonstration by dynamic sensory profile evaluation.

Food chemistry (2015-10-17)
Georgia Lytra, Sophie Tempere, Stéphanie Marchand, Gilles de Revel, Jean-Christophe Barbe
ABSTRACT

Our study focused on variations in wine aroma perception and molecular composition during tasting over a period of 30min. In parallel, dynamic analytical and sensory methods were applied to study changes in the wines' molecular and aromatic evolution. Dynamic sensory profile evaluations clearly confirmed the evolution of the wine's fruity notes during sensory analysis, highlighting significant differences for red-berry and fresh fruit as well as black berry and jammy fruit, after 5 and 15min, respectively. Dynamic analytical methods revealed a decrease in ester and dimethyl sulphide (DMS) concentrations in the first few minutes. Sensory profiles of aromatic reconstitutions demonstrated that the aromatic modulation of fruity notes observed during wine tasting was explained by changes in ester and DMS concentrations. These results revealed that variations in concentrations of DMS and esters during wine tasting had a qualitative impact, by modulating fruity aromas in red wine.

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
Ethyl 3-hydroxybutyrate, ≥97%, FG
Sigma-Aldrich
Dimethyl sulfide, natural, ≥99%, FCC, FG
Sigma-Aldrich
Hexyl acetate, 99%
Sigma-Aldrich
Ethanol, purum, secunda spirit, denaturated with 2% 2-butanone, S15, ~96% (based on denaturant-free substance)
Sigma-Aldrich
Ethyl isobutyrate, ≥98%, FCC, FG
Sigma-Aldrich
Ethyl isobutyrate, natural, ≥98%, FCC, FG
Sigma-Aldrich
Isoamyl acetate, natural, ≥97%, FCC, FG
Sigma-Aldrich
Isoamyl acetate, ≥95%, FCC, FG
Sigma-Aldrich
Thiophene, ≥99%
Sigma-Aldrich
Ethyl isobutyrate, 99%
Sigma-Aldrich
Dimethyl sulfide, ≥99%
Sigma-Aldrich
Dimethyl sulfide, anhydrous, ≥99.0%
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Ethyl alcohol, Pure, 190 proof, ACS spectrophotometric grade, 95.0%
Sigma-Aldrich
Dimethyl sulfide, redistilled, ≥99%, FCC, FG
Sigma-Aldrich
Ethanol, purum, fine spirit, denaturated with 2% 2-butanone, F25 MEK1, ~96% (based on denaturant-free substance)
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Ethanol, purum, absolute ethanol, denaturated with 2% 2-butanone, A15 MEK1, ≥99.8% (based on denaturant-free substance)
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Ethanol, purum, absolute ethanol, denaturated with 4.8% isopropanol, A15 IPA1, ≥99.8% (based on denaturant-free substance)
Sigma-Aldrich
Ethanol, ACS reagent, prima fine spirit, without additive, F15 o1
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Ethanol, purum, fine spirit, denaturated with 4.8% methanol, F25 METHYL1, ~96% (based on denaturant-free substance)
Sigma-Aldrich
Ethanol, purum, absolute ethanol, denaturated with 1% cyclohexane, A15 CYCLO1, ≥99.8% (based on denaturant-free substance)
Sigma-Aldrich
Hexyl acetate, ≥98%, FCC, FG
Sigma-Aldrich
Hexyl acetate, natural, ≥98%, FCC, FG
Sigma-Aldrich
Ethyl 3-hydroxybutyrate, ≥98%
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Ethyl alcohol, Pure, 200 proof, for molecular biology
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Ethyl alcohol, Pure, 190 proof, for molecular biology
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Ethyl alcohol, Pure, 200 proof, ACS reagent, ≥99.5%
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Sodium sulfate, anhydrous, free-flowing, Redi-Dri, ACS reagent, ≥99%
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Sodium sulfate, puriss., meets analytical specification of Ph. Eur., BP, USP, anhydrous, 99.0-100.5% (calc. to the dried substance)
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Sodium sulfate, ACS reagent, ≥99.0%, anhydrous, powder
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Sodium sulfate, anhydrous, free-flowing, Redi-Dri, ReagentPlus®, ≥99%