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  • Acetylation of aromatic ethers using acetic anhydride over solid acid catalysts in a solvent-free system. Scope of the reaction for substituted ethers.

Acetylation of aromatic ethers using acetic anhydride over solid acid catalysts in a solvent-free system. Scope of the reaction for substituted ethers.

Organic & biomolecular chemistry (2003-08-21)
Keith Smith, Gamal A el-Hiti, Anthony J Jayne, Michael Butters
ABSTRACT

The acetylation of aryl ethers using acetic anhydride in the presence of zeolites under modest conditions in a solvent-free system gave the corresponding para-acetylated products in high yields. The zeolite can be recovered, regenerated and reused to give almost the same yield as that given when fresh zeolite is used.

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
2-Chloroanisole, 98%