45299
Epoxide Hydrolase from Rhodococcus rhodochrous
lyophilized powder, beige, ≥0.2 U/g
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About This Item
CAS Number:
MDL number:
UNSPSC Code:
12352204
NACRES:
NA.54
Recommended Products
form
lyophilized powder
specific activity
≥0.2 U/g
color
beige
storage temp.
2-8°C
Biochem/physiol Actions
Epoxide hydrolase is an enantioselective catalyst for the hydrolytic kinetic resolution of epoxides.
Unit Definition
1 U corresponds to the amount of enzymes which hydrolizes 1 μmol (S)-NEPC [(2S,3S)-trans-3-phenyl-2-oxiranylmethyl-4-nitrophenyl carbonate, Prod. No. 04088] per minute at pH 8.0 and 25 °C
Other Notes
Asymmetric hydrolysis of epoxides to optically active diols
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Resp. Sens. 1
Storage Class Code
11 - Combustible Solids
WGK
WGK 1
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Certificates of Analysis (COA)
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Mischitz, M., et al.
Tetrahedron Asymmetry, 7, 2041-2041 (1996)
Hechtberger, P.
Tetrahedron Asymmetry, 4, 1161-1161 (1993)
E N Jacobsen
Accounts of chemical research, 33(6), 421-431 (2000-07-13)
The discovery of the metal salen-catalyzed asymmetric ring-opening (ARO) of epoxides is chronicled. A screening approach was adopted for the identification of catalysts for the addition of TMSN(3) to meso-epoxides, and the chiral (salen)CrN(3) complex was identified as optimal. Kinetic
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