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18735

Sigma-Aldrich

Hydrobromic acid solution

33 wt. % in acetic acid

Synonym(s):

Hydrogen bromide in acetic acid

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About This Item

Empirical Formula (Hill Notation):
HBr
Molecular Weight:
80.91
Beilstein:
3587158
MDL number:
MFCD00011323
UNSPSC Code:
12352106
PubChem Substance ID:
329751739
NACRES:
NA.21

Assay

31.5-34.5% (T)

Quality Level

100

form

liquid

concentration

33 wt. % in acetic acid

impurities

≤1% water (KFT)

density

1.40 g/mL at 20 °C

SMILES string

Br

InChI

1S/BrH/h1H

InChI key

CPELXLSAUQHCOX-UHFFFAOYSA-N

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General description

Hydrobromic acid solution (HBr) is a clear, yellow or brown colored liquid. Its reaction with K has been studied by a molecular beam technique.

Application

Hydrobromic acid solution may be used for the demethylation of 3,4-dimethoxy-6-bromonitrobenzene. Along with paraldehyde, it forms an efficient bromomethylating agent for benzene derivatives.
Hydrobromic acid solution may be used to infrared spectroscopic analysis of degree of N-deacetylation of chitosan.

Pictograms

CorrosionExclamation mark
GHS05,GHS07

Signal Word

Danger

Hazard Statements

H290,H314,H335

Hazard Classifications

Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Hydrogen Bromide-Acetic Acid Demethylation of 2, 3-Dimethoxy-6-bromobenzoic Acid. An Example of Concomitant Bromine Migration.
Pettit GR and Piatak DM.
The Journal of Organic Chemistry, 25(5), 721-725 (1960)
Regioselective bromomethylation of 1, 2-dialkylbenzenes.
Garg N and Lee TR
Synlett, 9(03), 310-312 (1998)
Study of chemical reaction mechanisms with molecular beams. The reaction of K with HBr.
Taylor EH and Datz S.
J. Chem. Phys., 23(9), 1711-1718 (1955)
Improved infrared spectroscopic method for the analysis of degree of N-deacetylation of chitosan.
Sabnis S and Block LH.
Polym. Bull., 39(1), 67-71 (1997)
Ahmed Hasbi et al.
FASEB journal : official publication of the Federation of American Societies for Experimental Biology, 28(11), 4806-4820 (2014-07-27)
Although the dopamine D1-D2 receptor heteromer has emerging physiological relevance and a postulated role in different neuropsychiatric disorders, such as drug addiction, depression, and schizophrenia, there is a need for pharmacological tools that selectively target such receptor complexes in order
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