M4141
Methanesulfonic acid solution
4 M (with 0.2% (w/v) tryptamine)
Synonym(s):
Sulfomethane
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About This Item
Linear Formula:
CH3SO3H
CAS Number:
Molecular Weight:
96.11
Beilstein:
1446024
EC Number:
MDL number:
UNSPSC Code:
12352209
PubChem Substance ID:
NACRES:
NA.21
Recommended Products
form
liquid
Quality Level
concentration
4 M (with 0.2% (w/v) tryptamine)
storage temp.
2-8°C
SMILES string
CS(O)(=O)=O
InChI
1S/CH4O3S/c1-5(2,3)4/h1H3,(H,2,3,4)
InChI key
AFVFQIVMOAPDHO-UHFFFAOYSA-N
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Application
For complete protein and peptide hydrolysis with tryptophan recovery. After hydrolysis the samples are diluted prior to amino acid analysis.
Packaging
Ampules sealed under argon.
Caution
air sensitive, store under inert conditions
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B - Skin Sens. 1 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
8A - Combustible, corrosive hazardous materials
WGK
WGK 2
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Luke F Gamon et al.
Redox biology, 36, 101586-101586 (2020-06-07)
The precise characterization and quantification of oxidative protein damage is a significant challenge due to the low abundance, large variety, and heterogeneity of modifications. Mass spectrometry (MS)-based techniques at the peptide level (proteomics) provide a detailed but limited picture due
Chris Twelves et al.
Breast cancer research and treatment, 148(3), 553-561 (2014-11-09)
Data from two phase 3 studies of eribulin were pooled in analyses initially requested by the European Medicines Agency to assess whether specific patient subgroups, previously treated with an anthracycline and a taxane, benefited from eribulin. Study 305/EMBRACE included women
Solvejg Jørgensen et al.
Physical chemistry chemical physics : PCCP, 15(14), 5140-5150 (2013-03-02)
The gas phase reaction between methane sulfonic acid (CH3SO3H; MSA) and the hydroxyl radical (HO), without and with a water molecule, was investigated with DFT-B3LYP and CCSD(T)-F12 methods. For the bare reaction we have found two reaction mechanisms, involving proton
Norio Murai et al.
Organic letters, 14(11), 2818-2821 (2012-05-18)
A one-pot primary aminomethylation of aryl halides, triflates, mesylates, and tosylates via Suzuki-Miyaura cross-coupling reactions with sodium phthalimidomethyltrifluoroborate followed by deamidation with ethylenediamine is reported.
Renata Solarska et al.
Nanoscale, 4(5), 1553-1556 (2012-02-01)
Nanostructuring of semiconductor films offers the potential means for producing photoelectrodes with improved minority charge carrier collection. Crucial to the effective operation of the photoelectrode is also the choice of a suitable electrolyte. The behaviour of the nanostructured WO(3) photoanodes
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