ALD00290

Sodium 2,2-dimethylpropylsulfinate

• Synonym(s): DMPS-Na
• Empirical Formula (Hill Notation): C₅H₁₁NaO₂S
• CAS Number: 51928-41-7
• Molecular Weight: 158.19
• UNSPSC Code: 41106514
• PubChem Substance ID: 329772649
• NACRES: NA.22

Properties

• form: solid
• Quality Level: 100
• reaction suitability: reaction type: C-C Bond Formation; reagent type: catalyst; reaction type: C-H Activation
• mp: >200 °C
• SMILES string: CC(C)(C)CS(O[Na])=O
• InChI: 1S/C5H12O2S.Na/c1-5(2,3)4-8(6)7;/h4H2,1-3H3,(H,6,7);/q;+1/p-1
• InChI key: KLBOBKWDKHOXNX-UHFFFAOYSA-M

Description

Application

The following Baran Sulfinate is a part of a toolbox of diversification reagents, which are ideal for the late-stage functionalization of nitrogen-containing heterocycles. The regioselectivity can be effectively tuned by modification of the pH and solvent selection.

Other Notes

Radical-Based Regioselective C-H Functionalization of Electron-Deficient Heteroarenes: Scope; Tunability; and Predictability

Safety Information

• Pictograms: GHS07
• Signal Word: Warning
• Hazard Statements: H319
• Precautionary Statements: P264 - P280 - P305 + P351 + P338 - P337 + P313
• Hazard Classifications: Eye Irrit. 2
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable