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Sigma-Aldrich

Ir[FCF3(CF3)ppy]2(dtbbpy)PF6

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About This Item

Empirical Formula (Hill Notation):
C44H34F20IrN4P
CAS Number:
2222402-20-0
Molecular Weight:
1221.93
UNSPSC Code:
12352101
NACRES:
NA.22

form

powder

Quality Level

100

reaction suitability

reaction type: Photocatalysis
reagent type: catalyst

mp

378 °C

Application

Ir[FCF3(CF3)ppy]2(dtbbpy)PF6 is a versatile photocatalyst that can be used for a variety of synthetic transformations including the α-arylation of alcohols.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Other Notes

Selective Hydrogen Atom Abstraction through Induced Bond Polarization: Direct α-Arylation of Alcohols through Photoredox, HAT, and Nickel Catalysis

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Product No.
Description
Pricing

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Jack Twilton et al.
Angewandte Chemie (International ed. in English), 57(19), 5369-5373 (2018-03-01)
The combination of nickel metallaphotoredox catalysis, hydrogen atom transfer catalysis, and a Lewis acid activation mode, has led to the development of an arylation method for the selective functionalization of alcohol α-hydroxy C-H bonds. This approach employs zinc-mediated alcohol deprotonation

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