905291

Rh₂(R-BTPCP)₄

• Synonym(s): Davies dirhodium catalyst, Dirhodium tetrakis((S,R)-1-(4-bromophenyl)-2,2-diphenylcyclopropanecarboxylate), Dirhodium tetrakis[(R)-1-(4-bromophenyl)-2,2- diphenylcyclopropane carboxylate], Tetrakis[(R)-(-)-[(1R)-1-(4-bromophenyl)-2,2-diphenylcyclopropanecarboxylato]dirhodium(II), Tetrakis[(R)-1-(4-bromophenyl)-2,2- diphenylcyclopropane carboxylato]dirhodium(II)
• Empirical Formula (Hill Notation): C₈₈H₆₄Br₄O₈Rh₂
• CAS Number: 1345974-62-0
• Molecular Weight: 1774.87
• UNSPSC Code: 12161600
• NACRES: NA.22

Properties

• form: powder or crystals
• mp: >300 °C

Description

Application

Rh catalyst developed by the Davies lab used for enantioselective cyclopropanations and C-H funcionalization under low catalyst loadings.

Other Notes

D2-Symmetric Dirhodium Catalyst Derived from a 1,2,2-Triarylcyclopropanecarboxylate Ligand: Design, Synthesis and Application

Enantioselective Synthesis of 2-Arylbicyclo[1.1.0]butane Carboxylates

Site-selective and stereoselective functionalization of non-activated tertiary C-H bonds

Safety Information

• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable