901742

Dimethyl[(1-pyrrolidinyl)phenyl]-amine nickel(II) chloride

≥95%

• Synonym(s): (^PyrN^MeNN)Ni-Cl, (SP-4-4)-Chloro[N₁,N₁-dimethyl-N₂-[2-(1-pyrrolidinyl-κN)phenyl]-1,2-benzenediaminato-κN₁,κN₂]nickel, Second-generation Nickamine
• Empirical Formula (Hill Notation): C₁₈H₂₂ClN₃Ni
• Molecular Weight: 374.53
• UNSPSC Code: 12352101

Properties

• Assay: ≥95%
• form: powder or crystals
• reaction suitability: core: nickel; reagent type: catalyst
• SMILES string: CN(C)C1=C(C=CC=C1)NC2=CC=CC=C2N3CCCC3.[Ni].Cl

Description

Application

As reported by Xile Hu′s lab, this nickel(II) pincer complex is an improvement from the first-generation Nickamine as an efficient Ni catalyst for Kumada and Suzuki-Miyaura cross-coupling of both nonactivated primary and secondary alkyl halides.

Other Notes

From Dimethylamine to Pyrrolidine: The Development of an Improved Nickel Pincer Complex for Cross-Coupling of Nonactivated Secondary Alkyl Halides

A Structure-Activity Study of Nickel NNN Pincer Complexes for Alkyl-Alkyl Kumada and Suzuki-Miyaura Coupling Reactions

Safety Information

• Storage Class Code: 13 - Non Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable