707230
tert-Butyldichlorophosphine solution
1.0 M in diethyl ether
Synonym(s):
(1,1-Dimethylethyl)phosphonous dichloride solution
About This Item
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form
liquid
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
concentration
1.0 M in diethyl ether
density
0.766 g/mL at 25 °C
functional group
phosphine
SMILES string
CC(C)(C)P(Cl)Cl
InChI
1S/C4H9Cl2P/c1-4(2,3)7(5)6/h1-3H3
InChI key
NMJASRUOIRRDSX-UHFFFAOYSA-N
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Application
- The preparation of Buchwald-type secondary phosphine oxide ligands
- Asymmetric hydrogenation
Reactant for the synthesis of:
- Alkali metal complexes
- P-Stereogenic compounds via kinetic deprotonation
- Ortho-trifluoromethylphenyl-substituted phosphines
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 1 - Skin Corr. 1B - STOT SE 3
Target Organs
Respiratory system
Supplementary Hazards
Storage Class Code
3 - Flammable liquids
WGK
WGK 3
Certificates of Analysis (COA)
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