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686018

Sigma-Aldrich

Sodium borohydride

greener alternative

hydrogen-storage grade, 98%

Synonym(s):

Sodium tetrahydridoborate

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About This Item

Linear Formula:
NaBH4
CAS Number:
Molecular Weight:
37.83
EC Number:
MDL number:
UNSPSC Code:
26111700
PubChem Substance ID:
NACRES:
NA.23

grade

hydrogen-storage grade

Assay

98%

form

powder

reaction suitability

reagent type: reductant

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

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mp

>300 °C (dec.) (lit.)

greener alternative category

SMILES string

[BH4-].[Na+]

InChI

1S/BH4.Na/h1H4;/q-1;+1

InChI key

YOQDYZUWIQVZSF-UHFFFAOYSA-N

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General description

Atomic number of base material: 11
Gravimetric hydrogen capacity of sodium borohydride can be up to 10.8%.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Application

Sodium borohydride (NaBH4) is a stable hydrogen carrier, which can be used as a chemical hydrogen storage material. It can also be used as an anodic fuel for alternative energy applications such as the fabrication of fuel cells. It can also be used in the reduction of graphene oxide in the presence of CaCl2 as a catalyst.
Sodium borohydride has promising application as a portable hydrogen storage material.

Analysis Note

Hydrogen content, XRD plots and metal purity data are available upon request.

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 3 Oral - Eye Dam. 1 - Repr. 1B - Skin Corr. 1B - Water-react 1

Supplementary Hazards

Storage Class Code

4.3 - Hazardous materials which set free flammable gases upon contact with water

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Owing to its high storage capacity (10.8 mass %), sodium borohydride (NaBH(4)) is a promising hydrogen storage material. However, the temperature for hydrogen release is high (>500 °C), and reversibility of the release is unachievable under reasonable conditions. Herein, we

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