All Photos(3)

Key Documents

View All Documentation

684821

1,2-Bis(phenylsulfinyl)ethane palladium(II) acetate

Name: 1,2-Bis(phenylsulfinyl)ethane palladium(II) acetate
Brand: ALDRICH

Synonym(s):

White catalyst

Sign Into View Organizational & Contract Pricing

All Photos(3)

About This Item

Empirical Formula (Hill Notation):

C₁₈H₂₀O₆PdS₂

CAS Number:

858971-43-4

Molecular Weight:

502.90

MDL number:

MFCD09842752

UNSPSC Code:

12161600

PubChem Substance ID:

329760926

NACRES:

NA.22

form

powder

reaction suitability

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
reaction type: C-H Activation

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

greener alternative category

Aligned,

storage temp.

−20°C

SMILES string

CC(=O)O[Pd]OC(C)=O.O=S(CCS(=O)c1ccccc1)c2ccccc2

InChI

1S/C14H14O2S2.2C2H4O2.Pd/c15-17(13-7-3-1-4-8-13)11-12-18(16)14-9-5-2-6-10-14;2*1-2(3)4;/h1-10H,11-12H2;2*1H3,(H,3,4);/q;;;+2/p-2

InChI key

SNNYSJNYZJXIFE-UHFFFAOYSA-L

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Find details here.

Application

White Catalyst: A Catalyst for Allylic C–H Oxidation and Amination

Macrolactonization via Hydrocarbon Oxidation

Catalyst for allylic C-H oxidation, useful for preparation of branched allylic esters, macrocycles, and amino alcohol derivatives.

Pictograms

GHS05

Signal Word

Danger

Hazard Statements

H318

Precautionary Statements

P280 - P305 + P351 + P338

Hazard Classifications

Eye Dam. 1

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Search for a COA

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Macrolactonization via hydrocarbon oxidation.

Kenneth J Fraunhoffer et al.

Journal of the American Chemical Society, 128(28), 9032-9033 (2006-07-13)

A novel Pd/sulfoxide-catalyzed macrolactonization reaction of linear omega-alkenoic acids is reported that proceeds via serial ligand-catalyzed allylic C-H oxidation. The scope of this macrolactonization appears to be very broad. Aryl, alkyl, and (Z)-alpha,beta-unsaturated acids are all competent nucleophiles for this

syn-1,2-Amino alcohols via diastereoselective allylic C-H amination.

Kenneth J Fraunhoffer et al.

Journal of the American Chemical Society, 129(23), 7274-7276 (2007-05-23)

Articles

White Catalyst

Developed by Professor M. Christina White and co-workers at the University of Illinois–Urbana, the “White catalyst” (684821) has been shown to be an exceptional catalyst for the functionalization of allylic carbon centers.

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service