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538973

Sigma-Aldrich

Tris(dibenzoylmethane) mono(5-amino-1,10-phenanthroline)europium (lll)

Synonym(s):

Europium(III) tris(1,3-diphenyl-1,3-propanedionato) mono(5-amino-1,10-phenanthroline)

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About This Item

Empirical Formula (Hill Notation):
C57H45EuN3O6
CAS Number:
352546-68-0
Molecular Weight:
1019.95
MDL number:
MFCD03093711
UNSPSC Code:
12352103
PubChem Substance ID:
24878373
NACRES:
NA.23

reaction suitability

reagent type: catalyst
core: europium

mp

163-168 °C (lit.)

λmax

244 nm in H2O

SMILES string

Nc1cc2cccnc2c3ncccc13.O=C(\C=C(/O[Eu](O\C(=C\C(=O)c4ccccc4)c5ccccc5)O\C(=C\C(=O)c6ccccc6)c7ccccc7)c8ccccc8)c9ccccc9

InChI

1S/3C15H12O2.C12H9N3.Eu/c3*16-14(12-7-3-1-4-8-12)11-15(17)13-9-5-2-6-10-13;13-10-7-8-3-1-5-14-11(8)12-9(10)4-2-6-15-12;/h3*1-11,16H;1-7H,13H2;/q;;;;+3/p-3/b3*14-11+;;

InChI key

AKNYTGVINNNCMK-RWBKAWJDSA-K

General description

Light emitting metal complex.

Application

Temperature-sensitive europium complexes of tris(dibenzoylmethane) mono(5-amino-1,10-phenanthroline)europium(III) [Eudatp] may be used to fabricate a dual optical sensor to detect oxygen and any change in temperature. This product may be used in the preparation of porphyrin–Eu-β-diketonate supramolecular nanostructures, and in the fabrication of silicon wafers grafted with europium complex.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKBZ3404V
MKBZ2669V
MKBZ1801V
MKBX9399V
MKBW6658V

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Dual optical sensor for oxygen and temperature based on the combination of time domain and frequency domain techniques
Hung L, et al.
Talanta null
Europium Complex Covalently Grafted on Si (100) Surfaces, Engineered with Covalent Polystyrene Nanostructures.
Cristaldi D, et al.
The Journal of Physical Chemistry C, 16213-16220 null
Europium Complex Covalently Grafted on Si (100) Surfaces, Engineered with Covalent Polystyrene Nanostructures.
Cristaldi D, et al.
The Journal of Physical Chemistry C null
Optical properties of porphyrin?Eu-?-diketonate supramolecular nanostructures.
Millesi S and Gulino A
Journal of Material Chemistry C null
Optical properties of porphyrin?Eu-?-diketonate supramolecular nanostructures.
Millesi S and Gulino A
Journal of Material Chemistry C, 5924-5930 null
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