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380520

Sigma-Aldrich

Ammonium tetraphenylborate

99%

Synonym(s):

Tetraphenylboron ammonium

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About This Item

Linear Formula:
NH4B(C6H5)4
CAS Number:
14637-34-4
Molecular Weight:
337.27
Beilstein:
3799683
MDL number:
MFCD00134523
UNSPSC Code:
12161600
PubChem Substance ID:
24863748
NACRES:
NA.22

Assay

99%

reaction suitability

core: boron
reagent type: catalyst

mp

220 °C (dec.) (lit.)

SMILES string

[H][N+]([H])([H])[H].c1ccc(cc1)[B-](c2ccccc2)(c3ccccc3)c4ccccc4

InChI

1S/C24H20B.H3N/c1-5-13-21(14-6-1)25(22-15-7-2-8-16-22,23-17-9-3-10-18-23)24-19-11-4-12-20-24;/h1-20H;1H3/q-1;/p+1

InChI key

ZWFYDLYRTYMBIL-UHFFFAOYSA-O

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Related Categories

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Beata Paczosa-Bator et al.
Talanta, 81(3), 1003-1009 (2010-03-20)
This paper focuses on the quantitative determination of the loss of the components from plastic membranes of ion-selective electrodes (ISEs) during contact with aqueous bathing solutions. The leaching processes, which affect the ISE responses, are rarely characterized by independent methods.
D C Kapsimali et al.
Talanta, 80(3), 1311-1317 (2009-12-17)
Two different derivatizing reagents were tested for the development of a fast and sensitive method for the determination of selenites (Se(IV)) in human urine. The reagents were sodium tetraethylborate (NaBEt(4)) and tetraphenylborate (NaBPh(4)), respectively, and the procedure is based on
Hajime Katano et al.
Analytical sciences : the international journal of the Japan Society for Analytical Chemistry, 28(12), 1153-1157 (2012-12-13)
A biopolymer ε-poly-L-lysine (εPL) exists as a fully protonated form (εPLH(n+)) in solutions at pH < 4. Around pH 3.5, at which the tetraphenylborate (TPB(-)) anion is not decomposed immediately, the εPLH(n+) cation associates with the TPB(-) anion to form
Aihui Liang et al.
Bioprocess and biosystems engineering, 34(5), 639-645 (2011-01-22)
In the pH 6.6 Na2HPO4-NaH2PO4 buffer solutions and in the presence of urease catalyst, urea can be decomposed to form NH4+. The NH4+ reacted with sodium tetraphenyl boron (NaTPB) to form the association particles that exhibited a resonance scattering (RS)
S I M Zayed et al.
Analytical sciences : the international journal of the Japan Society for Analytical Chemistry, 26(1), 45-49 (2010-01-13)
The construction and electrochemical response characteristics of two new polyvinyl chloride (PVC) membrane sensors for the determination of sibutramine hydrochloride were described. The sensors are based on the ion association complexes of sibutramine with sodium tetraphenylborate (NaTPB) or phosphotungstic acid
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