289345
Cesium fluoride
99.9% trace metals basis
Synonym(s):
NSC 84270
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About This Item
Empirical Formula (Hill Notation):
CsF
CAS Number:
Molecular Weight:
151.90
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.22
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Assay
99.9% trace metals basis
mp
682 °C (lit.)
density
4.115 g/mL at 25 °C (lit.)
SMILES string
[F-].[Cs+]
InChI
1S/Cs.FH/h;1H/q+1;/p-1
InChI key
XJHCXCQVJFPJIK-UHFFFAOYSA-M
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Related Categories
Application
Reactant for:
- Preparation of building blocks for synthesis of fluoroallylic compounds
- Synthesis of alcohols via hydrolysis of alkyl silyl ethers at neutral pH in buffered mixed organic-aqueous solutions
- Nucleophilic fluorination of alkynyliodonium salts to form fluorovinylic compounds
- Nucleophilic aromatic substitution (SNAr) reactions
Used in the successful synthesis of a single-crystal Dion-Jacobson phase, CsLaTa2O7, that has applications in photocatalysis and superconductivity.
Used as a base in a Suzuki cross-coupling synthesis of ortho-substituted biaryls. Also employed as a reagent for nucleophilic fluorination of primary halides and sulfonates in protic media such as tert-butyl and tert-pentyl alcohols.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Repr. 2 - STOT RE 2
Target Organs
Kidney,Adrenal gland
Supplementary Hazards
Storage Class Code
11 - Combustible Solids
WGK
WGK 2
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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The structures, stabilities, thermodynamic quantities, dissociation energies, infrared spectra, and electronic properties of CsF hydrated by water molecules are investigated by using density functional theory, Møller-Plesset second-order perturbation theory (MP2), coupled cluster theory with singles, doubles, and perturbative triples excitations
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