C-phosphanyl-C-chloroiminium salts as electrophilic carbene synthetic equivalents.

C-phosphanyl-C-chloroiminium salts as electrophilic carbene synthetic equivalents.

Chemical communications (Cambridge, England) (2002-10-26)

Nathalie Merceron, Antoine Baceiredo, Heinz Gornitzka, Guy Bertrand

RESUMEN

C-Phosphanyl-C-chloroiminium salts formally react as phosphonio(amino)carbenes with tert-butyl isocyanide and trimethylphosphine, and as R2NC+ with vinyl ether and diisopropylamine.

MATERIALES

Referencia del producto

Marca

Descripción del producto

324116

Sigma-Aldrich

Trimethylphosphine solution, 1.0 M in toluene