- A highly efficient titanium-based olefin polymerisation catalyst with a monoanionic iminoimidazolidide pi-donor ancillary ligand.
A highly efficient titanium-based olefin polymerisation catalyst with a monoanionic iminoimidazolidide pi-donor ancillary ligand.
Chemical communications (Cambridge, England) (2002-07-18)
Winfried P Kretschmer, Chris Dijkhuis, Auke Meetsma, Bart Hessen, Jan H Teuben
PMID12120146
RESUMEN
The titanium complex Cp[1,3-(2',6'-Me2C6H3)2(CH2N)2C=N]Ti(CH2Ph)2, with a monoanionic eta 1-iminoimidazolidide ancillary ligand, is shown to be a highly efficient catalyst for olefin polymerisation when activated with the Lewis acid B(C6F5)3.
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