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Merck

Oxazolidinone-promoted, torquoselective Nazarov cyclizations.

Organic letters (2012-03-30)
Daniel J Kerr, Michael Miletic, Jason H Chaplin, Jonathan M White, Bernard L Flynn
摘要

Oxazolidinones are powerful promoters of the Nazarov reaction, enabling the cyclization of conventionally resistant substrates to be achieved under mild conditions. They exert excellent regio- and torquoselective control in both the conventional Nazarov reaction giving cyclopentenones and in the "interrupted" Nazarov reaction, giving more highly substituted multistereocenter containing products.

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2-环戊烯-1-酮, 98%
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