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Key Documents

V900088

Sigma-Aldrich

1-甲基咪唑

Vetec, reagent grade, 98%

同義詞:

N-Methylimidazole

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About This Item

經驗公式(希爾表示法):
C4H6N2
CAS號碼:
分子量::
82.10
Beilstein:
105197
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:

等級

reagent grade

蒸汽壓力

0.4 mmHg ( 20 °C)

產品線

Vetec

化驗

98%

自燃溫度

977 °F

expl. lim.

15.7 %

折射率

n20/D 1.495 (lit.)

bp

198 °C (lit.)

mp

−6 °C (lit.)

密度

1.03 g/mL at 25 °C (lit.)

SMILES 字串

Cn1ccnc1

InChI

1S/C4H6N2/c1-6-3-2-5-4-6/h2-4H,1H3

InChI 密鑰

MCTWTZJPVLRJOU-UHFFFAOYSA-N

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法律資訊

Vetec is a trademark of Merck KGaA, Darmstadt, Germany

訊號詞

Danger

危險分類

Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Eye Dam. 1 - Repr. 2 - Skin Corr. 1B

儲存類別代碼

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

水污染物質分類(WGK)

WGK 2

閃點(°F)

197.6 °F - closed cup

閃點(°C)

92 °C - closed cup


分析證明 (COA)

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Pengfei Zhang et al.
Journal of chromatography. A, 1218(22), 3459-3465 (2011-04-19)
The development of mixed-mode stationary phase to achieve multiple separation capabilities in one column is very important for high performance liquid chromatography. In this paper, a new specific stationary phase based on grafting N-methylimidazolium to a monolithic silica column was
Bhaskar Sharma et al.
The journal of physical chemistry. A, 115(10), 1971-1984 (2011-02-22)
Quantum chemical [MP2(FULL)/6-311++G-(d,p)] calculations are done on the binding of hydrated Li(+), Na(+), K(+), Mg(2+), Cu(+), and Zn(2+) metal ions with biologically relevant heteroaromatics such as imidazole and methylimidazole. The computed interaction energies are found to be in good agreement
Zhan-Yong Wang et al.
The Journal of organic chemistry, 77(15), 6608-6614 (2012-07-19)
A well-defined NHC-Pd(II)-Im complex 1 was found to be an effective catalyst for the Suzuki-Miyaura coupling of aryl sulfonates including tosylates and phenylsulfonates with arylboronic acids, giving the desired coupling products in good to high yields. Acceptable yields can also
Sabesan Yoganathan et al.
Organic letters, 15(3), 602-605 (2013-01-19)
An efficient, one-pot, N-methylimidazole (NMI) accelerated synthesis of aromatic and aliphatic carbamates via the Lossen rearrangement is reported. NMI is a catalyst for the conversion of isocyanate intermediates to the carbamates. Moreover, the utility of arylsulfonyl chloride in combination with
Wen-Xin Chen et al.
The Journal of organic chemistry, 77(20), 9236-9239 (2012-10-02)
We report herein that amides are excellent N-sources in the NHC-Pd(II)-Im complex 1 catalyzed amination of aryl chlorides. In the presence of KO(t)Bu, various aryl chlorides and amides can react smoothly to give the corresponding aminated products in moderate to

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