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重要文件

T8637

Sigma-Aldrich

一磷酸硫胺氯化物 二水合物

同義詞:

氯化亚氨基磷酸酯

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About This Item

經驗公式(希爾表示法):
C12H18ClN4O4PS · 2H2O
CAS號碼:
分子量::
416.82
Beilstein:
3844977
EC號碼:
MDL號碼:
分類程式碼代碼:
12352107
PubChem物質ID:
NACRES:
NA.79

生物源

synthetic

品質等級

化驗

≥99.0% (HPLC)

形狀

powder

技術

HPLC: suitable

顏色

white to off-white

mp

190 °C

儲存溫度

2-8°C

SMILES 字串

[Cl-].Cc1ncc(C[n+]2csc(CCOP(O)(O)=O)c2C)c(N)n1

InChI

1S/C12H17N4O4PS.ClH/c1-8-11(3-4-20-21(17,18)19)22-7-16(8)6-10-5-14-9(2)15-12(10)13;/h5,7H,3-4,6H2,1-2H3,(H3-,13,14,15,17,18,19);1H

InChI 密鑰

GUGWNSHJDUEHNJ-UHFFFAOYSA-N

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應用

盐酸硫胺素一磷酸盐氯化物二水合物已被用作高效液相色谱(HPLC)法定量测定植物渗出液中的硫胺素和评估其纯度的标准品。

生化/生理作用

硫胺素一磷酸激酶(TMP)是硫胺素一磷酸激酶(EC 2.7.4.16)的底物,也是硫胺素焦磷酸(TPP)的前体。TPP是一种参与糖和氨基酸分解代谢的辅酶。
硫胺素一磷酸盐(TMP)可用作硫胺素磷酸激酶(EC 2.7.4.16)的底物,同时也是硫胺素焦磷酸盐(TPP)的前体。TPP是一种参与糖和氨基酸分解代谢的辅酶。TMP是硫胺素焦磷酸盐水解形成硫胺素的中间体。

象形圖

Exclamation mark

訊號詞

Warning

危險聲明

危險分類

Skin Sens. 1

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 1

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Gloves, type N95 (US)


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Carsten Wrenger et al.
Biological chemistry, 387(1), 41-51 (2006-02-25)
Vitamin B1 (thiamine) is an essential cofactor for several key enzymes of carbohydrate metabolism. Mammals have to salvage this crucial nutrient from their diet to complement their deficiency of de novo synthesis. In contrast, bacteria, fungi, plants and, as reported
M Héroux et al.
Metabolic brain disease, 11(1), 81-88 (1996-03-01)
There is a growing body of evidence to suggest that thiamine neurochemistry is disrupted in Alzheimer's Disease (AD). Studies in autopsied brain tissue from neuropathologically proven AD patients reveal significantly reduced activities of the thiamine phosphate dephosphorylating enzymes thiamine diphosphatase
M Héroux et al.
Neurochemical research, 20(1), 87-93 (1995-01-01)
Thiamine phosphate esters (thiamine monophosphate-TMP; thiamine diphosphate-TDP and thiamine triphosphate-TTP) were measured as their thiochrome derivatives by High Performance Liquid Chromatography in the brains of pyrithiamine-treated rats at various stages during the development of thiamine deficiency encephalopathy. Severe encephalopathy was
New Research and Developments of Water-Soluble Vitamins (2018)
Structural studies of thiamin monophosphate kinase in complex with substrates and products
McCulloch KM, et al.
Biochemistry, 47(12), 3810-3821 (2008)

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