跳轉至內容
Merck
全部照片(1)

文件

402990

Sigma-Aldrich

一氯化碘

ACS reagent, 1.10±0.1 I/Cl ratio basis

同義詞:

氯化碘

登入查看組織和合約定價


About This Item

線性公式:
ICl
CAS號碼:
分子量::
162.36
EC號碼:
MDL號碼:
分類程式碼代碼:
12352300
PubChem物質ID:
NACRES:
NB.24

等級

ACS reagent

形狀

solid or liquid

雜質

≤0.005% insolubles

bp

97.4 °C (lit.)

溶解度

acetic acid: soluble(lit.)
acetone: soluble(lit.)
alcohol: soluble(lit.)
carbon disulfide: soluble(lit.)

密度

3.24 g/mL at 25 °C (lit.)

儲存溫度

2-8°C

SMILES 字串

ClI

InChI

1S/ClI/c1-2

InChI 密鑰

QZRGKCOWNLSUDK-UHFFFAOYSA-N

尋找類似的產品? 前往 產品比較指南

一般說明

Iodine monochloride is an interhalogen compound. It forms various complexes with ethyl, isopropyl and t-butylbenzenes. Equilibrium constants for the formation of these complexes have been evaluated. It affords electrically conducting solution on dissolution in polar solvents. Its reaction with thymidine, 3-mono- and 3,3′,5′-trialkylsubstitued thymidine showed that it helps in deglycosylation, anomerization and isomerization of thymidine.

應用

Iodine monochloride (ICl) may be employed for the halogenation of methoxy and dimethoxybenzenes. It may be used for the synthesis of flavones.
Iodine monochloride may be used in the synthesis of the following:
  • 2-(4-haloisoquinolin-1-yl)ethanol derivatives
  • 5-iodosalicylaldehydes
  • 5-aryl-6-iodo-8-phenylpyrazolo[1,5-c]-1,2,4-triazolo[4,3-a]pyrimidines
  • (±)-1-cyclohexyl-4-iodo-3-methoxybutan-1-ol
  • (±)-4-Iodo-3-methoxy-1-phenylbutan-1-ol

象形圖

CorrosionExclamation mark

訊號詞

Danger

危險聲明

危險分類

Eye Dam. 1 - Skin Corr. 1B - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

8B - Non-combustible corrosive hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable


分析證明 (COA)

輸入產品批次/批號來搜索 分析證明 (COA)。在產品’s標籤上找到批次和批號,寫有 ‘Lot’或‘Batch’.。

已經擁有該產品?

您可以在文件庫中找到最近購買的產品相關文件。

存取文件庫

客戶也查看了

Slide 1 of 2

1 of 2

Brisbois RG, et al.
e-EROS Encyclopedia of Reagents for Organic Synthesis. (2013)
Synthesis and Electrophilic Substitutions of Novel Pyrazolo [1, 5-c]-1, 2, 4-triazolo [4, 3-a] pyrimidines.
Atta KFM.
Molecules (Basel), 16(8), 7081-7096 (2011)
Eric Stefan et al.
Tetrahedron, 69(36), 7706-7712 (2013-09-24)
Ether transfer methodology is capable of stereoselectively generating 1,3-diol mono- and diethers in good yield. Surprisingly, allylic and benzylic substrates provide none of the desired products when exposed to previously optimized conditions of iodine monochloride. Herein, second-generation activation conditions for
Synthesis of Luminescent Ethynyl-Extended Regioisomers of Borate Complexes Based on 2-(2'-Hydroxyphenyl) benzoxazole.
23 Massue J, et al.
Chemistry (Weinheim An Der Bergstrasse, Germany), 19(17), 5375-5386 (2013)
Eagleson M.
Concise Encyclopedia Chemistry, 477-477 (1994)

我們的科學家團隊在所有研究領域都有豐富的經驗,包括生命科學、材料科學、化學合成、色譜、分析等.

聯絡技術服務