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重要文件

88561

Sigma-Aldrich

2,2′-硫二乙醇

purum, ≥95.0% (GC)

同義詞:

2,2′-硫代双乙醇, 双(2-羟乙基)硫醚, 硫代二甘醇, 硫代双乙醇标准液 CRM

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About This Item

線性公式:
S(CH2CH2OH)2
CAS號碼:
分子量::
122.19
Beilstein:
1236325
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

等級

purum

品質等級

化驗

≥95.0% (GC)

形狀

liquid

折射率

n20/D 1.521
n20/D 1.5215 (lit.)

bp

164-166 °C/20 mmHg (lit.)

mp

−16 °C (lit.)

密度

1.221 g/mL at 25 °C (lit.)

官能基

hydroxyl
thioether

SMILES 字串

OCCSCCO

InChI

1S/C4H10O2S/c5-1-3-7-4-2-6/h5-6H,1-4H2

InChI 密鑰

YODZTKMDCQEPHD-UHFFFAOYSA-N

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應用

2,2′-Thiodiethanol is used in the preparation of a wide range of gold complexes, which include Au(I) based catalysts such as chloro(triphenylphosphine)gold(I) [Au(PPh3)Cl], chloro(dimethyl sulfide)gold(I) [Au(SMe2)Cl] and chloro[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]gold(I) [IPrAuCl]. It can also be used to build calixarene frameworks.

象形圖

Exclamation mark

訊號詞

Warning

危險聲明

防範說明

危險分類

Eye Irrit. 2

儲存類別代碼

10 - Combustible liquids

水污染物質分類(WGK)

WGK 1

閃點(°F)

235.4 °F - closed cup

閃點(°C)

113 °C - closed cup

個人防護裝備

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


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Gold (I)?Catalyzed Intermolecular Cyclopropanation of Enynes with Alkenes: Trapping of Two Different Gold Carbenes.
Lopez S, et al.
Angewandte Chemie (International Edition in English), 118(36), 6175-6178 (2006)
Networking of calixcrowns: From heteronuclear endo/exocyclic coordination polymers to a photoluminescence switch.
Lee J Y, et al.
Journal of the American Chemical Society, 130(42), 13838-13839 (2008)
A general synthesis for gold (I) complexes.
Al?Sa'Ady A K, et al.
Inorg. Synth., 23, 191-194 (1985)
Binding and extraction of alkali and alkaline earth metals by nano-baskets of calix [4] arene-1, 2-crown-3.
Mokhtari B and Pourabdollah K
Journal of Inclusion Phenomena and Macrocyclic Chemistry, 73(1-4), 269-277 (2012)
Stereo-and regioselective gold-catalyzed hydroamination of internal alkynes with dialkylamines.
Hesp K D, et al.
Journal of the American Chemical Society, 132(51), 18026-18029 (2010)

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