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(R)-(+)-α-甲基苄胺

for chiral derivatization, LiChropur, ≥99.0%

同義詞:

(R)-(+)-1-苯乙胺

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About This Item

線性公式:
C6H5CH(CH3)NH2
CAS號碼:
分子量::
121.18
Beilstein:
2410916
EC號碼:
MDL號碼:
分類程式碼代碼:
12000000
PubChem物質ID:
NACRES:
NA.22

等級

for chiral derivatization

品質等級

蒸汽壓力

0.5 mmHg ( 20 °C)

化驗

≥99.0% (sum of enantiomers, GC)
≥99.0%

形狀

liquid

光學活性

[α]20/D +30±1°, c = 10% in ethanol

光學純度

enantiomeric ratio: ≥99.5:0.5 (GC)

品質

LiChropur

技術

HPLC: suitable

折射率

n20/D 1.526 (lit.)
n20/D 1.528

bp

187-189 °C (lit.)

密度

0.952 g/mL at 20 °C (lit.)

儲存溫度

2-8°C

SMILES 字串

C[C@@H](N)c1ccccc1

InChI

1S/C8H11N/c1-7(9)8-5-3-2-4-6-8/h2-7H,9H2,1H3/t7-/m1/s1

InChI 密鑰

RQEUFEKYXDPUSK-SSDOTTSWSA-N

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一般說明

(R)-(+)-α-Methylbenzylamine is a high quality, useful chiral derivatization reagent for all analytical applications, specific to GC in the chiral field. It is specially selected to meet the requirements for derivatization reagents for enantiomeric excess determinations.

應用

(R)-(+)-a-Methylbenzylamine also known as (R)-(+)-1-Phenylethylamine may be used in resolution of a chiral arylalkylamine involving high-conversion enantioselective condensation with capric acid followed by hydrolysis to yield corresponding (R)-(+)-amide.

其他說明

用于测定酸对映体纯度的手性胺

推薦產品

Discover LiChropur reagents ideal for HPLC or LC-MS analysis

法律資訊

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

象形圖

CorrosionExclamation mark

訊號詞

Danger

危險聲明

危險分類

Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B

儲存類別代碼

8A - Combustible corrosive hazardous materials

水污染物質分類(WGK)

WGK 1

閃點(°F)

158.0 °F - closed cup

閃點(°C)

70 °C - closed cup

個人防護裝備

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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R.W. Souter
Chromatographic Separations of Stereoisomers null
Easy-on, easy-off?resolution of chiral 1-phenylethylamine catalyzed by Candida antarctica lipase B.
Torres-Gavilan, A., et al.
Tetrahedron Asymmetry, 18.22, 2621-2624 (2007)
W.H. Pirkle and J. Finn et al.
Asymmetric Synthesis, 1 (1983)
Alejandra León et al.
Journal of natural products, 75(5), 859-864 (2012-05-12)
The enantiomeric lactams (-)-8, (+)-8, (+)-9, and (-)-9 were formed by the reaction of the dimeric phthalide rac-tokinolide B (rac-3) with (R)-(+)-α-methylbenzylamine and (S)-(-)-α-methylbenzylamine. The absolute configurations of compounds 8 and 9 were assigned by experimental and theoretically calculated electronic
Paul E Harrington et al.
Current medicinal chemistry, 14(28), 3027-3034 (2008-01-29)
The calcium sensing receptor (CaR) is a G protein-coupled receptor (GPCR) that plays a fundamental role in serum calcium homeostasis. The CaR is expressed on the chief cells of the parathyroid gland and is responsible for controlling the secretion of

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