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About This Item
線性公式:
Mo(CO)6
CAS號碼:
分子量：:
264.00
EC號碼:
MDL號碼:
分類程式碼代碼:
12352103
PubChem物質ID:
NACRES:
NA.23
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一般說明
Molybdenum hexacarbonyl is a colorless compound that sublimates and decomposes without melting at 150oC. It has an octahedral structure. Inherent sublimation of molybdenum hexacarbonyl permits it to perform as an active liquefaction catalyst. To form a catalyst it is adsorbed on dehydroxylated alumina forming subcarboyls.
應用
Alumina supported molybdenum hexacarbonyl acts as an active catalyst. It is used to synthesize MoO and MoC nanowires by electron beam induced deposition.
訊號詞
Danger
危險聲明
危險分類
Acute Tox. 3 Inhalation
儲存類別代碼
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
水污染物質分類（WGK）
WGK 3
閃點（°F）
Not applicable
閃點（°C）
Not applicable
個人防護裝備
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
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Microstructural analysis and Transport Properties of MoO and MoC nanostructures prepared by focused electron beam-induced deposition
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Scientific Reports, 4 (2014)
An investigation of the chemistry of molybdenum hexacarbonyl on thin dehydroxylated alumina films in ultrahigh vacuum
Catalysis Letters, 91(1-2), 83-88 (2003)
In situ generation of carbon monoxide from solid molybdenum hexacarbonyl. A convenient and fast route to palladium-catalyzed carbonylation reactions.
Nils-Fredrik K Kaiser et al.
Journal of combinatorial chemistry, 4(2), 109-111 (2002-03-12)
John Spencer
Future medicinal chemistry, 2(2), 161-168 (2011-03-24)
Microwave-mediated chemistry, involving the reduction of nitroarenes with molybdenum hexacarbonyl as a stoichiometric reducing agent, has been employed in the synthesis of a range of anilines. Many of these reactions exhibit high levels of chemoselectivity, tolerating unsaturation, steric hindrance and
Paul Nissenson et al.
Physical chemistry chemical physics : PCCP, 8(40), 4700-4710 (2006-10-19)
While there is increasing evidence for unique chemical reactions at interfaces, there are fewer data on photochemistry at liquid-vapor junctions. This paper reports a comparison of the photolysis of molybdenum hexacarbonyl, Mo(CO)(6), in 1-decene either as liquid droplets or in
文章
Spin-based electronic (spintronic) devices offer significant improvement to the limits of conventional charge-based memory and logic devices which suffer from high power usage, leakage current, performance saturation, and device complexity.
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