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Merck
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重要文件

34115

Supelco

BDE No 77 溶液

50 μg/mL in isooctane, analytical standard

同義詞:

3,3′,4,4′-四溴二苯醚 溶液, 3,3′,4,4′-TetraBDE, PBDE 77

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About This Item

經驗公式(希爾表示法):
C12H6Br4O
CAS號碼:
分子量::
485.79
EC號碼:
MDL號碼:
分類程式碼代碼:
41116107
PubChem物質ID:
NACRES:
NA.24

等級

analytical standard

品質等級

儲存期限

limited shelf life, expiry date on the label

濃度

50 μg/mL in isooctane

技術

HPLC: suitable
gas chromatography (GC): suitable

應用

environmental

形式

single component solution

儲存溫度

2-8°C

SMILES 字串

Brc1ccc(Oc2ccc(Br)c(Br)c2)cc1Br

InChI

1S/C12H6Br4O/c13-9-3-1-7(5-11(9)15)17-8-2-4-10(14)12(16)6-8/h1-6H

InChI 密鑰

RYGLOWMCGZHYRQ-UHFFFAOYSA-N

一般說明

BDE No 77 is a contaminant found to be persistent in the environment with very low acute toxicity. It belongs to the class of polybrominated diphenyl ethers. It can find wide applications as additive flame-retardants in consumer products ranging from textiles to polymers.

應用

BDE No 77 may be used as an analytical reference standard to determine analyte present in river sediments using gas chromatography coupled to mass spectrometry (GC-MS) and selective pressurized liquid extraction followed by gas chromatography coupled to negative ion chemical ionization-mass spectrometry (GC-NCI-MS).
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

其他說明

The customer needs to make sure that the standard is homogeneous, this can be achieved by shaking, vortexing , or sonicating the ampoule before opening the ampoule. Care should be taken when opening the ampoule to avoid any injuries from the broken glass.
The standard should be transferred to a clean and appropriate vial or flask using clean pipettes or micro pipettes. The vial should be immediately capped to avoid any loss or evaporation of the solvent.
After opening the ampoule, the standard should not be stored or kept in the ampoule. To preserve the integrity of the product, the standard should be transferred to an appropriate vial that must be capped and stored according to the recommendation on the Certificate of Analysis.

訊號詞

Danger

危險分類

Aquatic Acute 1 - Aquatic Chronic 1 - Asp. Tox. 1 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Central nervous system

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 2

閃點(°F)

10.4 °F - closed cup

閃點(°C)

-12 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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分析證明 (COA)

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存取文件庫

Determination of decabromodiphenyl ether in sediments using selective pressurized liquid extraction followed by GC-NCI-MS.
Eljarrat E, et al.
Analytical and Bioanalytical Chemistry, 378(3), 610-614 (2004)
GC / MS analysis of polybrominated diphenyl ethers in fish collected from the Inland Sea of ??Seto, Japan.
Akutsu K, et al.
Chemosphere, 44(6), 1325-1333 (2001)
Karim Zuhra et al.
Cells, 8(8) (2019-08-07)
Hydrogen sulfide (H2S) is an endogenously produced signaling molecule. The enzymes 3-mercaptopyruvate sulfurtransferase (MST), partly localized in mitochondria, and the inner mitochondrial membrane-associated sulfide:quinone oxidoreductase (SQR), besides being respectively involved in the synthesis and catabolism of H2S, generate sulfane sulfur

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