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等級
reagent
品質等級
蒸汽密度
2.8 (vs air)
蒸汽壓力
160 mmHg ( 20 °C)
產品線
ReagentPlus®
化驗
99%
形狀
liquid
自燃溫度
590 °F
expl. lim.
5 %
dilution
(for general lab use)
折射率
n20/D 1.446 (lit.)
bp
83 °C (lit.)
mp
−104 °C (lit.)
溶解度
water: insoluble
密度
0.811 g/mL at 25 °C (lit.)
SMILES 字串
C1CCC=CC1
InChI
1S/C6H10/c1-2-4-6-5-3-1/h1-2H,3-6H2
InChI 密鑰
HGCIXCUEYOPUTN-UHFFFAOYSA-N
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一般說明
Cyclohexene is a cyclic alkene. Kinetics of its reaction with hydrogen in gas and liquid phases over different palladium catalysts supported on silica gel and alumina (temperature range = 264 to 308K and hydrogen pressures = 4 to 89kPa) was investigated. Cyclohexene is formed during the batch-wise partial hydrogenation of benzene over ruthenium catalysts in the presence of an aqueous zinc sulphate solution. Cyclohexene undergoes enantioselective catalytic oxidation in the presence of hydrogen peroxide over environment-friendly peroxytungstate-organic complex catalysts to afford adipic acid. Selective hydrogenation of benzene has been reported to afford cyclohexene. It is an important precursor for the preparation of various chemicals such as cyclohexanol, cyclohexene hydroperoxide, etc.
應用
Cyclohexene has been used to investigate the kinetics of its liquid-phase hydrogenation reaction in the presence of Pd-Al catalyst supported on biomorphic carbon. It may be used for the industrial preparation of cyclohexanol.
法律資訊
ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
訊號詞
Danger
危險分類
Acute Tox. 4 Oral - Aquatic Chronic 2 - Asp. Tox. 1 - Flam. Liq. 2
儲存類別代碼
3 - Flammable liquids
水污染物質分類（WGK）
WGK 2
閃點（°F）
1.4 °F
閃點（°C）
-17 °C
個人防護裝備
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
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Catalytic hydrogenation of cyclohexene: 3. Gas-phase and liquid-phase reaction on supported palladium.
Gonzo EE and Boudart M.
J. Catal., 52(3), 462-471 (1978)
Hydration of cyclohexene with solid acid catalysts.
Zhang H, et al.
Chemical Engineering Science, 57(2), 315-322 (2002)
Partial liquid phase hydrogenation of benzene to cyclohexene over ruthenium catalysts in the presence of an aqueous salt solution: I. Preparation, characterization of the catalyst and study of a number of process variables.
Struijk J, et al.
Applied Catalysis A: General, 83(2), 263-295 (1992)
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