1.01245

Isopentyl nitrite

extra pure stabilized with potassium carbonate

• 同義詞: Isopentyl nitrite, iso-Amyl nitrite, iso-Pentyl nitrite, Nitrous acid isoamyl ester
• 經驗公式（希爾表示法）: C₅H₁₁NO₂
• CAS號碼: 110-46-3
• 分子量：: 117.15
• MDL號碼: MFCD00002057
• 分類程式碼代碼: 12352108
• 酶委員會索引編號: 203-770-8
• NACRES: NA.22

屬性

• 品質等級: 200
• 形狀: liquid
• 自燃溫度: 208 °C
• 效力: 505 mg/kg LD₅₀, oral (Rat)
• bp: 97-99 °C/1013 hPa
• 轉變溫度: flash point -18 °C
• 密度: 0.872 g/cm³ at 20 °C
• 儲存溫度: 2-8°C
• SMILES 字串: N(=O)OCCC(C)C
• InChI: 1S/C5H11NO2/c1-5(2)3-4-8-6-7/h5H,3-4H2,1-2H3
• InChI 密鑰: OWFXIOWLTKNBAP-UHFFFAOYSA-N

描述

應用

• Deaminative coupling of benzylamines and arylboronic acids: Research demonstrated the use of isopentyl nitrite in the deaminative coupling of benzylamines and arylboronic acids, showcasing its application in creating complex molecules for pharmaceutical and chemical manufacturing processes (Sirvinskaite, Reisenbauer, and Morandi, 2023).
• Syntheses of Arylazo Phosphine Oxides and Phosphonates: Utilizing isopentyl nitrite, research facilitated the synthesis of arylazo phosphine oxides and phosphonates via N-P bond formation under blue LED light conditions, contributing to developments in organophosphorus chemistry (Shen et al., 2022).

分析報告

Total nitrites (GC): ≥ 97.0 % (a/a)
Identity (IR-spectrum): conforms
Free acid: conforms
Density (d 20 °C/ 4 °C): 0.8720 - 0.8770
Non volatile matter: ≤ 0.04 %

安全資訊

• 象形圖: GHS02,GHS05,GHS07,GHS08
• 訊號詞: Danger
• 危險聲明: H225 - H302 + H332 - H314 - H317 - H341
• 防範說明: P210 - P280 - P301 + P312 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• 危險分類: Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Muta. 2 - Skin Corr. 1B - Skin Sens. 1
• 儲存類別代碼: 3 - Flammable liquids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: -4.0 °F - closed cup
• 閃點（°C）: -20 °C - closed cup