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Merck
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重要文件

M39105

Sigma-Aldrich

甲基环己烯酮

98%, Stabilized

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About This Item

線性公式:
CH3C6H7(=O)
CAS號碼:
分子量::
110.15
Beilstein:
1560601
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

化驗

98%

折射率

n20/D 1.494 (lit.)

bp

199-200 °C (lit.)

密度

0.971 g/mL at 25 °C (lit.)

SMILES 字串

CC1=CC(=O)CCC1

InChI

1S/C7H10O/c1-6-3-2-4-7(8)5-6/h5H,2-4H2,1H3

InChI 密鑰

IITQJMYAYSNIMI-UHFFFAOYSA-N

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應用

3-Methyl-2-cyclohexenone is an insect sex pheromone of the Douglas-fir beetle. It can be used as a starting material:
  • In the total synthesis of (−)-ar-tenuifolene, a naturally occurring aromatic sesquiterpene.
  • To synthesize an organic building block 2-trimethylsilyl-3-methyl-cyclohexenone.
  • In the total synthesis of natural diterpenoids (+)-taiwaniaquinone H and (+)-dichroanone.

象形圖

Exclamation mark

訊號詞

Warning

危險聲明

危險分類

Acute Tox. 4 Oral

儲存類別代碼

10 - Combustible liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

154.4 °F - closed cup

閃點(°C)

68 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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分析證明 (COA)

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Catalytic asymmetric formal total synthesis of (+)-dichroanone and (+)-taiwaniaquinone H
Li L-Q, et al.
Tetrahedron Letters, 55(43), 5960-5962 (2014)
Catalytic enantioselective total synthesis of (−)-ar-Tenuifolene
Shaw K, et al.
Tetrahedron Letters, 61(20), 151850-151850 (2020)
Aldrichimica Acta, 16, 41-41 (1983)
Shoichiro Horita et al.
Chembiochem : a European journal of chemical biology, 16(3), 440-445 (2015-02-03)
(4R,6R)-Actinol can be stereo-selectively synthesized from ketoisophorone by a two-step conversion using a mixture of two enzymes: Candida macedoniensis old yellow enzyme (CmOYE) and Corynebacterium aquaticum (6R)-levodione reductase. However, (4S)-phorenol, an intermediate, accumulates because of the limited substrate range of

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