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Key Documents

D223204

Sigma-Aldrich

杜醌

97%

同義詞:

2,3,5,6-四甲基-1,4-苯醌, 四甲基对苯醌

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About This Item

經驗公式(希爾表示法):
C10H12O2
CAS號碼:
分子量::
164.20
Beilstein:
1909128
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

化驗

97%

形狀

powder

mp

110-112 °C (lit.)

SMILES 字串

CC1=C(C)C(=O)C(C)=C(C)C1=O

InChI

1S/C10H12O2/c1-5-6(2)10(12)8(4)7(3)9(5)11/h1-4H3

InChI 密鑰

WAMKWBHYPYBEJY-UHFFFAOYSA-N

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一般說明

二醌是一种有机氧化剂,属于1,4-苯醌类,用于氧化还原流动Li–O2电池。

應用

  • 杜醌在光合作用研究中的作用:一项对紫色细菌光合反应中心的研究表明,当杜醌被纳入QA结合位点时,会影响同位素编辑的FTIR差光谱,这对理解光合作用中的能量转换过程至关重要(Zhao et al., 2013)。
  • 杜醌作为分子离子源的研究:研究表明,杜醌可以产生分子负离子,在质谱研究分子电离和寿命方面具有潜力(Khvostenko et al., 2012)。
  • 杜醌在生化传感器中的应用:利用光系统II单层优化金电极表面的研究表明,杜醌在增强传感器响应方面起着关键作用,适用于生化传感器技术(Maly et al., 2005)。
  • 杜醌类同系物的细胞毒性研究一项对包括杜罗醌在内的14种对苯醌同系物的比较研究,使用定量结构-毒性关系来评估大鼠肝细胞和PC12细胞的细胞毒性,适用于化学生产中的安全性评估(Siraki et al., 2004)。

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves


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分析證明 (COA)

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Marilyn P Merker et al.
American journal of physiology. Lung cellular and molecular physiology, 290(3), L607-L619 (2005-10-26)
The objective of this study was to examine the impact of chronic hyperoxic exposure (95% O2 for 48 h) on intact bovine pulmonary arterial endothelial cell redox metabolism of 2,3,5,6-tetramethyl-1,4-benzoquinone (duroquinone, DQ). DQ or durohydroquinone (DQH2) was added to normoxic
Bingsheng Zhou et al.
Aquatic toxicology (Amsterdam, Netherlands), 77(2), 136-142 (2006-01-18)
Toxicity of many waterborne organic contaminants to aquatic organisms is mediated through oxidative damages resulting from the production of reactive oxygen species (ROS). Using duroquinone as a model ROS inducer, we carried out in vitro and in vivo experiments to
Said H Audi et al.
American journal of physiology. Lung cellular and molecular physiology, 289(5), L788-L797 (2005-07-05)
NAD(P)H:quinone oxidoreductase 1 (NQO1) plays a dominant role in the reduction of the quinone compound 2,3,5,6-tetramethyl-1,4-benzoquinone (duroquinone, DQ) to durohydroquinone (DQH2) on passage through the rat lung. Exposure of adult rats to 85% O2 for > or =7 days stimulates
Xiao-Hui Duan et al.
The Journal of chemical physics, 120(21), 10025-10032 (2004-07-23)
Photoinduced electron transfer of the model system composed of vitamin E and duroquinone has been investigated using time-dependent density functional theory. Calculations for the excited states tell that the photoexcitation of the model system can directly yield the charge transfer
J Maly et al.
Analytical and bioanalytical chemistry, 381(8), 1558-1567 (2005-04-12)
Mass transport of the bulk of the analyte to the electrode and through the bioactive layer can be significantly improved by use of the nanoelectrode array and defined arrangement of protein film. This phenomenon has been studied by (i) atomic-force

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