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重要文件

D198501

Sigma-Aldrich

2,4-二硝基酚

moistened with water, ≥98.0%

同義詞:

α-二硝基酚, 2,4-DNP, DNP

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About This Item

線性公式:
(O2N)2C6H3OH
CAS號碼:
分子量::
184.11
Beilstein:
1246142
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

蒸汽密度

6.35 (vs air)

品質等級

化驗

≥98.0%

包含

≥15% water

mp

108-112 °C (lit.)

SMILES 字串

Oc1ccc(cc1[N+]([O-])=O)[N+]([O-])=O

InChI

1S/C6H4N2O5/c9-6-2-1-4(7(10)11)3-5(6)8(12)13/h1-3,9H

InChI 密鑰

UFBJCMHMOXMLKC-UHFFFAOYSA-N

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應用

2,4-二硝基苯酚(DNP)可用于:
  • 作为催化还原反应的反应物。
  • 通过将羧酸转化为二硝基苯基(DNP)酯来激活羧酸。
  • 通过三氟甲磺酸铪催化异丁酸酐发生酰化反应制备相应的酯。
  • 作为有效的助催化剂,可提高天然伯氨基酸衍生的伯胺有机催化剂的活性和对映选择性,从而直接进行不对称的醇醛缩合反应。
  • 作为亚磷酰胺与核苷反应中四唑类的替代活化剂。

訊號詞

Danger

危險分類

Acute Tox. 2 Oral - Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Aquatic Acute 1 - Desen. Expl. 4 - STOT RE 1

儲存類別代碼

4.1B - Flammable solid hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable


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分析證明 (COA)

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HPLC Analysis of Phenols on SUPELCOSIL™ LC-8

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