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等級
sublimed grade
品質等級
描述
μh ≈ 1.1 x 10-6 cm2 V−1 s−1
μe ≈ 5.7 x 10-6 cm2 V−1 s−1
化驗
≥97% (HPLC)
損耗
0.5% TGA, > 300 °C (weight loss)
mp
236 °C
溶解度
chloroform: soluble
dichloromethane: soluble
toluene: soluble
λmax
266 nm±5 nm in dichloromethane
螢光
λem 298 nm±10 nm in dichloromethane
軌道能量
HOMO 6.79 eV
LUMO 2.52 eV
SMILES 字串
[Si](c4ccc(cc4)[P](=O)(c6ccccc6)c5ccccc5)(c3ccccc3)(c2ccccc2)c1ccccc1
InChI
1S/C36H29OPSi/c37-38(30-16-6-1-7-17-30,31-18-8-2-9-19-31)32-26-28-36(29-27-32)39(33-20-10-3-11-21-33,34-22-12-4-13-23-34)35-24-14-5-15-25-35/h1-29H
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應用
4,4′,4′′-Tris(N-(naphthalen-2-yl)-N-phenyl-amino)-triphenylamine (TSPO1), also known as diphenyl(4-(triphenylsilyl)phenyl)phosphine oxide, is popularly used as a solution-processable phosphorescent host in optoelectronic devices. It has a μh around 1.1 x 10-6 cm2 V−1 s−1 and a μe of about 5.7 x 10-6 cm2 V−1 s−1.
儲存類別代碼
11 - Combustible Solids
水污染物質分類(WGK)
WGK 3
閃點(°F)
Not applicable
閃點(°C)
Not applicable
RSC advances, 8(31), 17025-17033 (2018-05-09)
Two bipolar host materials, 8-(9H-carbazol-9-yl)-5-(pyridin-2-yl)-5H-pyrido[3,2-b]indole (CzCbPy) and 5-(6-(9H-carbazol-9-yl)pyridin-2-yl)-8-(9H-carbazol-9-yl)-5H-pyrido[3,2-b]indole (2CzCbPy), were synthesized for deep blue thermally activated delayed fluorescence organic light emitting diodes (TADF OLEDs). Both CzCbPy and 2CzCbPy hosts possess bipolar characteristic with high polarity, which results in high delayed
ACS applied materials & interfaces, 11(1), 26-30 (2018-12-14)
The development of highly efficient blue organic light-emitting diodes (OLEDs) with good stability is currently the most important issue in OLED displays and lighting. This paper reports an efficient blue fluorescent OLED based on a deep-blue-emitting phosphorescent sensitizer [(dfpysipy)2Ir(mpic)] and
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