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重要文件

932469

Sigma-Aldrich

4,4′,4′′-Tris(N-(naphthalen-2-yl)-N-phenyl-amino)-triphenylamine

同義詞:

TSPO1, Diphenyl(4-(triphenylsilyl)phenyl)phosphine oxide

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About This Item

經驗公式(希爾表示法):
C36H29OPSi
CAS號碼:
分子量::
536.67
MDL號碼:
分類程式碼代碼:
12352116
NACRES:
NA.23

等級

sublimed grade

品質等級

描述

μh ≈ 1.1 x 10-6 cm2 V−1 s−1
μe ≈ 5.7 x 10-6 cm2 V−1 s−1

化驗

≥97% (HPLC)

損耗

0.5% TGA, > 300 °C (weight loss)

mp

236  °C

溶解度

chloroform: soluble
dichloromethane: soluble
toluene: soluble

λmax

266 nm±5 nm in dichloromethane

螢光

λem 298 nm±10 nm in dichloromethane

軌道能量

HOMO 6.79 eV 
LUMO 2.52 eV 

SMILES 字串

[Si](c4ccc(cc4)[P](=O)(c6ccccc6)c5ccccc5)(c3ccccc3)(c2ccccc2)c1ccccc1

InChI

1S/C36H29OPSi/c37-38(30-16-6-1-7-17-30,31-18-8-2-9-19-31)32-26-28-36(29-27-32)39(33-20-10-3-11-21-33,34-22-12-4-13-23-34)35-24-14-5-15-25-35/h1-29H

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應用

4,4′,4′′-Tris(N-(naphthalen-2-yl)-N-phenyl-amino)-triphenylamine (TSPO1), also known as diphenyl(4-(triphenylsilyl)phenyl)phosphine oxide, is popularly used as a solution-processable phosphorescent host in optoelectronic devices. It has a μh around 1.1 x 10-6 cm2 V−1 s−1 and a μe of about 5.7 x 10-6 cm2 V−1 s−1.

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable


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