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Merck
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Key Documents

932450

Sigma-Aldrich

红荧烯

≥99% (HPLC)

同義詞:

5,6,11,12-四苯基并四苯

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About This Item

經驗公式(希爾表示法):
C42H28
CAS號碼:
分子量::
532.67
Beilstein:
1917339
MDL號碼:
分類程式碼代碼:
12352005
NACRES:
NA.21

等級

sublimed grade

品質等級

化驗

≥99% (HPLC)

光學活性

[α]/D

損耗

0.5% TGA, > 250 °C (weight loss)

mp

330-335 °C (lit.)

溶解度

THF: soluble
chloroform: soluble
toluene: soluble

λmax

299 nm

螢光

λex 221-227 nm; λem ≥35000 nm (in 0.005g/l, Heptane)
λex 296-302 nm; λem ≥95000 nm (in 0.005g/l, Heptane)
λex 457-463 nm; λem ≥5000 nm (in 0.005g/l, Heptane)
λex 485-491 nm; λem ≥9000 nm (in 0.005g/l, Heptane)
λex 520-526 nm; λem ≥9000 nm (in 0.005g/l, Heptane)
λem 553 nm±10 nm in THF

軌道能量

HOMO 5.4 eV 
LUMO 3.2 eV 

&lambda ;

in THF

紫外吸收

λ: 299 nm±5 nm Amax

SMILES 字串

c1ccc(cc1)-c2c3ccccc3c(-c4ccccc4)c5c(-c6ccccc6)c7ccccc7c(-c8ccccc8)c25

InChI

1S/C42H28/c1-5-17-29(18-6-1)37-33-25-13-14-26-34(33)39(31-21-9-3-10-22-31)42-40(32-23-11-4-12-24-32)36-28-16-15-27-35(36)38(41(37)42)30-19-7-2-8-20-30/h1-28H

InChI 密鑰

YYMBJDOZVAITBP-UHFFFAOYSA-N

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應用

5,6,11,12-Tetraphenylnaphthacene, also known as Rubrene, can be used in studies such as organic electronics and optoelectronics. Rubrene is widely used as an organic emitter material in OLED devices due to its high photoluminescence quantum yield and excellent electroluminescent properties. It emits intense red-orange light, making it suitable for red-emitting OLEDs. It exhibits excellent charge transport properties, allowing it to be used as an organic semiconducting material in OFET devices. Rubrene has been studied for potential applications in organic photovoltaic devices. It can be used in research areas in photovoltaics and sensors.
5,6,11,12-Tetraphenylnaphthacene, also known as Rubrene, is a solution-processable small molecular semiconductor. It is often used in chemiluminescence research and transition metal complex ligation. In OLED devices. it′s used as yellow fluorescent dopant.
用于化学发光研究和过渡金属络合物形成的试剂。

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable


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Sarah Wieghold et al.
The journal of physical chemistry letters, 11(3), 601-607 (2020-01-03)
Recent advances in perovskite-sensitized photon upconversion via triplet-triplet annihilation (TTA) in rubrene have yielded several unanswered questions about the underlying mechanism and processes occurring at the interface. In particular, the near-infrared perovskite emission is not significantly quenched and a rapid

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