931950

Sodium perchlorate

anhydrous, ≥99.9% trace metals basis

• 同義詞: Sodium Perchlorate, Hyperchloric acid sodium salt
• 經驗公式（希爾表示法）: ClNaO₄
• CAS號碼: 7601-89-0
• 分子量：: 122.44
• MDL號碼: MFCD00003480
• 分類程式碼代碼: 12352302
• NACRES: NA.23

屬性

• 等級: anhydrous; battery grade
• 品質等級: 100
• 化驗: ≥99.9% trace metals basis
• 形狀: powder
• 雜質: ≤1000 ppm (trace metals analysis)
• pH值: 6.0-8.0 (25 °C, 5%, aq.sol.)
• mp: 482 °C
• 溶解度: H₂O: 209 g/dL at 15 °C
• 負離子痕跡: chloride (Cl^-): ≤30 ppm; sulfate (SO₄^2-): ≤20 ppm
• 正離子痕跡: Fe: ≤5 ppm; K: ≤500 ppm
• 應用: battery manufacturing
• SMILES 字串: [Na+].[Cl](=O)(=O)(=O)[O-]
• InChI: 1S/ClHO4.Na/c2-1(3,4)5;/h(H,2,3,4,5);/q;+1/p-1
• InChI 密鑰: BAZAXWOYCMUHIX-UHFFFAOYSA-M

描述

一般說明

Anhydrous sodium perchlorate is a white crystalline solid. It is hygroscopic and absorbs water to form its monohydrate. Anhydrous sodium perchlorate is highly soluble in water, and soluble in a range of polar organic solvents such as methanol, ethanol, acetone, carbonates (including ethylene carbonate, dimethyl carbonate, propylene carbonate, and diethyl carbonate), and ethers (including dimethoxyethane, tetrahydrofuran, and triethylene glycol dimethyl ether). It is insoluble in benzene, chloroform, and toluene.

應用

The major application of anhydrous sodium perchlorate is as an electrolyte in sodium-ion batteries. It is popular because of its solubility in ethers and carbonates, its wide electrochemical stability window (e.g. from 0 to 5 V vs Na+/Na in propylene carbonate, triglyme, or diethylcarbonate)[1], and its compatibility with a wide range of materials. It has been used in batteries with hard-carbon anodes[2], mesoporous carbon anodes[3], sodium cobalt oxide cathodes (Na_xCoO₂)[4], sodium vanadium oxide cathodes (Na_xVO₂)[5], titanium dioxide cathodes[6], and emerging materials like high-entropy layered oxide cathodes[7].

包裝

10 g in glass bottle
25 g in glass bottle

安全資訊

• 象形圖: GHS03,GHS08,GHS07
• 訊號詞: Danger
• 危險聲明: H271,H302,H319,H373
• 防範說明: P210 - P220 - P260 - P301 + P312 - P305 + P351 + P338 - P314
• 危險分類: Acute Tox. 4 Oral - Eye Irrit. 2 - Ox. Sol. 1 - STOT RE 2
• 標靶器官: Thyroid
• 儲存類別代碼: 5.1A - Strongly oxidizing hazardous materials
• 水污染物質分類（WGK）: WGK 1