931845

GenOx-PJ

• 同義詞: 3-Oxo-2-tosyl-2,3-dihydro-1H-1λ₃-benzo[d][1,2]iodazol-1-yl acetate
• 經驗公式（希爾表示法）: C₁₆H₁₄INO₅S
• CAS號碼: 2243393-44-2
• 分子量：: 459.26
• 分類程式碼代碼: 12352200
• NACRES: NA.21

屬性

• 形狀: powder
• 品質等級: 100
• mp: >300 °C
• 官能基: iodo
• 儲存溫度: −20°C

描述

應用

GenOx-PJ is an iodine(III) based oxidant developed by Genentech as part of a robust method of forming C-O bonds through direct coupling of carboxylic acids with alcohols. When used with a Ru(II) photocatalyst, GenOx-PJ is active in the decarboxylative coupling of a broad range of carboxylic acids--including primary, secondary, tertiary, as well as peptides--with alcohols. By this method, GenOx-PJ enables a direct approach in utilizing simple, readily available substrates to perform this type of coupling, and providing many synthetic applications.

其他說明

A Platform for Decarboxylative Couplings via Photoredox Catalysis: Direct Access to Carbocations from Carboxylic Acids for Carbon−Oxygen Bond Formation

安全資訊

• 儲存類別代碼: 11 - Combustible Solids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: Not applicable
• 閃點（°C）: Not applicable