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Key Documents

931055

Sigma-Aldrich

tBuXPhos Pd G3 ChemBeads

同義詞:

[(2-Di-tert-butylphosphino-2′,4′,6′-triisopropyl-1,1′-biphenyl)-2-(2′-amino-1,1′-biphenyl)] palladium(II) methanesulfonate, tBuXPhos-Pd-G3

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About This Item

經驗公式(希爾表示法):
C42H58NO3PPdS
CAS號碼:
分子量::
794.37
NACRES:
NA.82

化驗

~6 wt.% loading of catalyst

品質等級

形狀

solid

反應適用性

reagent type: catalyst
reaction type: Cross Couplings

標籤範圍

~6 wt. % loading of catalyst

SMILES 字串

O=S([O-][Pd+2]1(P(C(C)(C)C)(C(C)(C)C)C2=CC=CC=C2C3=C(C(C)C)C=C(C(C)C)C=C3C(C)C)[C-]4=C(C5=C(N1)C=CC=C5)C=CC=C4)(C)=O

InChI

1S/C29H45P.C12H10N.CH4O3S.Pd/c1-19(2)22-17-24(20(3)4)27(25(18-22)21(5)6)23-15-13-14-16-26(23)30(28(7,8)9)29(10,11)12;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;/h13-21H,1-12H3;1-6,8-9H,13H2;1H3,(H,2,3,4);/q;;;+1/p-1

InChI 密鑰

SQQOHCLJPLSJGX-UHFFFAOYSA-M

相關類別

一般說明

tBuXPhos Pd G3 is a third generation (G3) Buchwald precatalyst. It is air, moisture and thermally-stable and is highly soluble in a wide range of common organic solvents. It has long life in solutions. tBuXPhos Pd G3 is an excellent reagent for Buchwald-Hartwig cross-coupling reaction. Some of its unique features include lower catalyst loadings, shorter reaction time, efficient formation of the active catalytic species and accurate control of ligand: palladium ratio.

For larger scale uses, product also available in powdered form (762229)

應用

tBuXPhos Pd G3 may be used to synthesize 4-cyano-7-azaindole from 4-chloro-7-azaindole by cyanation reaction. It may also be used for the α-arylation reaction of acetate esters at room temperature.

ChemBeads are chemical coated glass beads. ChemBeads offer improved flowability and chemical uniformity perfect for automated solid dispensing and high-throughput experimentation. The method of creating ChemBeads uses no other chemicals or surfactants allowing the user to accurately dispense sub-milligram amounts of chemical.

Learn more about ChemBeads products

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable


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