930059

S-Phenyl methanethioate

• 同義詞: Phenyl thioCORMate, Phenyl thioformate
• 經驗公式（希爾表示法）: C₇H₆OS
• CAS號碼: 27064-03-5
• 分子量：: 138.19
• MDL號碼: MFCD32756471
• 分類程式碼代碼: 12352101
• NACRES: NA.06

屬性

• 形狀: liquid
• 品質等級: 100
• 折射率: n/D 1.586
• 密度: 1.134 g/mL
• 官能基: thioether
• 儲存溫度: −20°C
• SMILES 字串: [H]C(SC1=CC=CC=C1)=O
• InChI: 1S/C7H6OS/c8-6-9-7-4-2-1-3-5-7/h1-6H
• InChI 密鑰: ITJOOMDVHPTIRB-UHFFFAOYSA-N

描述

應用

S-phenyl methanethioate is an effective CO releasing molecule (CORM) developed by the lab of Sarah Tasker as part of a series of thioformate based CORMs called thioCORMates. p-NO₂ phenyl thioformate generates CO over the course of several minutes to allow for on-demand generation of CO for variety of reactions.

This and the other thioCORMates are cost effective CORMs that when activated with simple amines, can be used to generate a near quantitative amount of CO safely without the usage of gas cylinders. These are compatible with a variety of carbonylation reactions, as well as existing COware glassware and components.

ThioCORMate: Tunable and Cost-Effective Carbon Monoxide-Releasing Molecule

Learn more about CO releasing molecules from Prof. Skrydstrup

安全資訊

• 象形圖: GHS07
• 訊號詞: Warning
• 危險聲明: H315,H319,H335
• 防範說明: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• 危險分類: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• 標靶器官: Respiratory system
• 儲存類別代碼: 10 - Combustible liquids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: 221.0 °F
• 閃點（°C）: 105 °C