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Merck
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Key Documents

911623

Sigma-Aldrich

2-(2,4-Difluorophenyl)-5-methoxypyridine

≥95%

同義詞:

dF(OMe)ppy

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About This Item

經驗公式(希爾表示法):
C12H9F2NO
CAS號碼:
分子量::
221.20
分類程式碼代碼:
12352101

化驗

≥95%

形狀

powder

反應適用性

reaction type: Photocatalysis
reagent type: catalyst

mp

79-81 °C

應用

2-(2,4-Difluorophenyl)-5-methoxypyridine is a ligand used for the preparation of Ir(III) photocatalysts.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable


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Chi Chip Le et al.
Journal of the American Chemical Society, 137(37), 11938-11941 (2015-09-04)
In this study we demonstrate that molecular fragments, which can be readily coupled via a simple, in situ RO-C═OR bond-forming reaction, can subsequently undergo metal insertion-decarboxylation-recombination to generate Csp(2)-Csp(3) bonds when subjected to metallaphotoredox catalysis. In this embodiment the conversion
David J P Kornfilt et al.
Journal of the American Chemical Society, 141(17), 6853-6858 (2019-04-16)
Copper oxidative addition into organohalides is a challenging two-electron process. In contrast, formal oxidative addition of copper to Csp2 carbon-bromine bonds can be accomplished by employing latent silyl radicals under photoredox conditions. This novel paradigm for copper oxidative addition has

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