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911178

Sigma-Aldrich

PS-750-M

greener alternative

solution, 3 wt. % in H2O

同義詞:

FI-750-M solution

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About This Item

線性公式:
(C2H4O)nC18H33NO3
CAS號碼:
2135447-74-2
分類程式碼代碼:
12352200
NACRES:
NA.22

形狀

liquid

環保替代產品特色

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

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濃度

3 wt. % in H2O

折射率

n/D 1.3373

密度

0.9931 g/mL

環保替代類別

Aligned,

儲存溫度

2-8°C

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相關類別

一般說明

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced to increase catalytic efficiency and also acts as an environmentally benign and sustainable amphiphile. Click here for more information.

應用

PS-750-M 3% solution in water is a custom surfactant developed in the Handa lab.
PS-750-M allows for a variety of reactions, including challenging cross-couplings and monofluorination of indoles, to be conducted in water.

其他說明

Micelle-Enabled Palladium Catalysis for Convenient sp2-sp3 Coupling of Nitroalkanes with Aryl Bromides in Water Under Mild Conditions

Shielding Effect of Micelle for Highly Effective and Selective Monofluorination of Indoles in Water

儲存類別代碼

10 - Combustible liquids

水污染物質分類（WGK）

WGK 3

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分析證明 (COA)

Lot/Batch Number
MKCN4826
MKCN4827

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Micelle-Enabled Palladium Catalysis for Convenient sp2-sp3 Coupling of Nitroalkanes with Aryl Bromides in Water Under Mild Conditions.
Brals J, et al.
ACS Catalysis, 7245-7250 (2017)
Micelle-Enabled Palladium Catalysis for Convenient sp2-sp3 Coupling of Nitroalkanes with Aryl Bromides in Water Under Mild Conditions.
Brals J, et al.
ACS Catalysis, 7(10), 7245-7250 (2017)
Lucie Finck et al.
The Journal of organic chemistry, 83(14), 7366-7372 (2018-02-10)
Using micelles of FI-750-M, visible light, photocatalysts, and inexpensive halogenating reagents, such as N-bromosuccinimide and N-chlorosuccinimde, selective oxyhalogenations of alkynes were achieved in water under very mild conditions. No halogenation at the aromatic rings was detected, and control experiments revealed
Pranjal P Bora et al.
ChemSusChem, 12(13), 3037-3042 (2019-03-06)
Highly selective direct monofluorination of indoles and arenes was developed through an approach that allows site-specific solubility of substrate and fluorine source in the micelle. This approach was highly selective for a broad range of substrates with excellent functional group

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